Antimonyl Potassium Tartrate: Physical Features, Properties, and Chemical Profile

What is Antimonyl Potassium Tartrate?

Antimonyl Potassium Tartrate, known in many labs and industries as potassium antimony tartrate, comes with a solid reputation for both usefulness and risk. This compound, with the chemical formula K2Sb2(C4H2O6)2·3H2O, has a bit of a legacy. Going by the synonym “tartar emetic,” it’s found its way into everything from laboratory chemical sets to hard industrial processes, especially those dealing with dyes and textiles.

Physical Structure and Appearance

Expect to encounter Antimonyl Potassium Tartrate as colorless, efflorescent crystals or occasionally as shiny flakes. Each crystal feels slightly slippery in the hand, a feature that comes from the hydrate molecules locked inside. They dissolve well in water, forming a clear, often almost syrupy solution. Typical density hovers around 2.6 g/cm³ for the solid, though it can feel denser to the touch due to its crystalline habit. The flakes tend to break easily, partly because the layers stack weakly, another point labs consider during handling. Whether supplied as fine powder, large pearls, or pressed solid cakes, each form brings distinct challenges for storage and measurement.

Specifications, Molecular Details, and Formula

With a molecular formula of C4H4KO7Sb, this compound draws attention for its blend of organic and inorganic traits. At the core, potassium cations balance negative charges from the tartrate and antimonyl ions, each part playing a role in the compound’s solubility and reactivity profiles. Chemically, it acts as a chelating agent, grabbing onto metal ions in solution, which gives it that old-school place in textile mordanting and analytical chemistry. Its molar mass of about 333.94 g/mol puts it in the middle range for common inorganic salts. Unlike many salts that cake up in humid air, this material’s crystalline structure tends to resist clumping if stored with care.

Material Forms: Flakes, Powder, Solution, and Crystal

Antimonyl Potassium Tartrate pops up as everything from chunky flakes to fine, almost talc-like powder. The industry often prefers solid, crystalline forms for shipping—these resist moisture and physical agitation better than loose powders. A batch delivered as pearls or large crystals usually indicates fresh preparation, while powder means it’s been processed further downstream. In solution, users see it as a clear, colorless liquid, much like sugar water but far from safe to handle casually. People moving between forms need to watch for dust and splashing; every bit is potent.

HS Code and Raw Material Considerations

On international manifests, this chemical falls under HS Code 2918.29, which covers miscellaneous salts of organic acids. Documentation matters: this code controls everything from tariffs to storage restrictions. Manufacturers start with raw antimony trioxide and tartaric acid, combining these under hot, aqueous conditions and introducing potassium salts to form the final compound. The process calls for precision, as a little shift in pH or temperature can swing the yield and purity. Raw materials, especially antimony compounds, often raise red flags for toxicity and sourcing, since antimony mining leaves a hefty environmental footprint.

Properties: Density, Solubility, and Reactivity

Antimonyl Potassium Tartrate stands out for its impressive water solubility—upwards of 170 g/L at room temperature—making it easy to mix but tricky to clean up in the event of a spill. Its density, usually noted around 2.6 g/cm³ for solid crystals, points to a substantial, weighty feel. Chemically, it stays relatively stable at room temperature, only breaking down under strong acids or through heating above 200°C. This resilience makes it suitable for precise roles in analysis, where it reliably keeps to spec under normal lab conditions. One of its main features, chelation, explains why it bonds readily to heavy metals, and why wastewater from sites handling the stuff often requires extra treatment.

Safe Handling, Hazard, and Health Notes

Here’s a reality check from years dealing with lab stockrooms: handle Antimonyl Potassium Tartrate with respect, not complacency. This compound carries a reputation for harming the body—classified as hazardous, with antimony-based toxicity affecting the gastrointestinal system and, in severe exposures, the heart. Inhalation or skin contact, especially with the fine powder, leads to irritation, and accidental ingestion has proven fatal in clinical literature. For years, tartrate salts figured on poison schedules, only handled by trained professionals. Every workshop or warehouse dealing in these raw materials must enforce gloves, eye protection, and fume hoods. Spilled powder or solution should mean emergency protocols—neutralize, contain, and collect for hazardous waste. Regular audits and employee training reduce the chance of accident, but the risk runs persistently high.

Solutions and Alternatives

Efforts to find replacements for toxic heavy metal reagents like Antimonyl Potassium Tartrate continue, especially with rising workplace safety expectations. Some industries swap out these chemicals for less dangerous, organic-based complexes or green chelators that break down after use without leaving harmful residues. Investment in closed systems—a reality for textile and chemical processing sites—can keep employee exposure close to zero and ensure all waste routes are tightly controlled. For labs, microscale experiments or digital analysis sometimes step in, sidestepping gallons of hazardous solutions. A practical approach also means regular health monitoring for those still exposed, catching any early signs of chronic effects.