9-Octadecenoic Acid (Z)- Ester with 2,2-bis(hydroxymethyl)-1,3-propanediol: Properties, Uses, and Safety

What is 9-Octadecenoic Acid (Z)- Ester with 2,2-bis(hydroxymethyl)-1,3-propanediol?

9-Octadecenoic acid (Z)- ester with 2,2-bis(hydroxymethyl)-1,3-propanediol, commonly known as a specific type of synthetic ester, represents an interesting chemical that blends a fatty acid backbone with a triol structure. This compound gets a lot of attention in material science, formulation chemistries, and even the food industry. Its chemical structure brings together oleic acid—a monounsaturated fatty acid—and trimethylolpropane. The Z configuration refers to the double bond’s natural “cis” orientation, which influences the compound’s flexibility, lubricity, and temperature stability. Both raw materials—oleic acid (C18H34O2) and trimethylolpropane (C6H14O3)—are common building blocks in industrial chemistry. Making this ester usually involves controlled esterification, driving off water and yielding a molecule that’s valued both for its specific chemical behavior and environmentally benign profile compared to older petroleum-based lubricants or additives.

Products and Fields of Application

You often spot this ester in lubricants, plasticizers, hydraulic fluids, and sometimes even in product formulations where skin feel or low toxicity matter a lot, like cosmetics or specialty polymers. Industrial users appreciate its ability to serve as a functional fluid, greasing up machines and materials without the health and environmental baggage that some legacy chemicals carry. Because it holds up well under varying temperatures, this ester shows up in synthetic oils for cars, precision gears, and industrial conveyor belts. Its molecular stability also makes it a go-to option for thermally sensitive operations, such as plastic molding or extruding. In my experience with oils and lubricants, esters like this make a notable difference—they usually resist breakdown or gumming up, keeping equipment running smoother for longer and reducing the need for toxic additives or frequent maintenance cycles.

Properties and Specifications

This ester is an organic molecule with the formula C27H52O6, though actual molecular weight or structure depends on how many acid chains attach to the central triol. The product's density usually stays close to 0.96-0.98 g/cm³ at standard temperature, but slight specification variations occur from supplier to supplier. You’ll find it in several physical forms: clear to pale yellow liquid, thick oily solid, waxy flakes, or tiny pearls depending on processing and storage. In large totes or drums, the pure liquid has a bland odor and slightly oily feel that’s distinct from petrochemicals. At room temperature, the substance maintains its fluidity, though chilling it below 10°C might cause partial solidification, and extended freezing produces brittle, crystalline solids. Purity often sits between 97-99%, depending on residual moisture and purification grade, and water solubility sits near zero—this stuff stays stubbornly hydrophobic, floating on water or forming beads when mixed.

Structure and Chemical Behavior

The core of this molecule—a central carbon attached to three alkyl chains—provides a unique blend of toughness and flexibility. The ester linkages resist hydrolysis under normal atmospheric conditions, but strong acids or bases split them up. Saponification (soap-making) kicks in only under intense alkaline conditions. Heat tolerance usually reaches up to 250°C before thermal decomposition threatens, substantially higher than basic mineral oils. The presence of double bonds in the fatty acid chains delivers good lubricity, especially in demanding environments where both load-bearing and chemical inertness count. The molecular size and shape help reduce viscosity loss at higher temperatures, keeping machinery protected even when running non-stop in harsh conditions.

HS Code, Regulatory, and Safe Handling

On the trade side, 9-Octadecenoic acid (Z)- ester with 2,2-bis(hydroxymethyl)-1,3-propanediol typically carries HS Code 291570, falling under organic esters and their derivatives. Customs and importers often require detailed documentation with shipment, focusing on purity, intended use, and whether the batch contains any hazardous impurities. Bulk shipments call for proper labeling—hazard class, UN number, and any relevant CAS number must stay visible for safe transportation and storage. This ester does not pose a significant threat under normal handling, but standard chemical safety rules apply. Gloves, splash goggles, and ventilation keep accidental contact or inhalation risks low, especially in production workshops. Bulk spills can turn slick and cause slip hazards, so cleanup involves absorbent mats and proper disposal according to local regulations. Compared to volatile organic solvents or mineral-based oils, the ester has a far lower risk profile, but ingestion or prolonged skin contact should always be avoided. From my time working in material science labs, taking even benign esters seriously means safer, more sustainable operations.

Molecular Formula, Density, and Physical Appearance

The molecular weight for a typical triester product sits near 472 g/mol. In practice, specific density and viscosity range depend on esterification completeness. Finished product appears as a nearly colorless or faintly yellow oil, with measured density between 0.96 and 0.98 grams per cubic centimeter. Bulk shipments may exhibit slight variations in color due to trace impurities, but top grade stocks are nearly water-clear. The solidified form, seen in cold storage or winter transport, tends toward white, crumbly flakes, which quickly melt back to fluid at room temperature. Powders and pearls show up in some specialty chemical packages where tight control over dosing or dispersal is required. Always store tightly sealed to avoid air or moisture pickup, as slow oxidation risks rendering the material cloudy or foul-smelling over time.

Safe, Hazardous, Harmful, and Environmental Notes

Compared to traditional petroleum-based additives or heavy metal-laced plasticizers, this ester stands out for its lower toxicity and friendlier environmental impact. It fails to bioaccumulate in organisms and breaks down into natural fatty acids plus small alcohols under environmental pressures. Standard handling precautions still apply—direct ingestion causes mild gastrointestinal upset at most, and prolonged skin contact may provoke local irritation. In industrial settings, proper ventilation prevents minor vapor exposure, though volatility remains low. This compound does not qualify as acutely hazardous, but large spills need containment to prevent slip or wastewater issues. Disposal typically involves controlled incineration or biodegradation, not landfill dumping. Hands-on work with these esters taught me that reliable personal protective equipment—gloves, goggles, aprons—removes nearly all routine risks, and local authorities mostly care about proper waste stream management, not workplace toxicity.

Role of Raw Materials and Quality Control

Raw material purity shapes every batch. Oleic acid must test free of pesticide residues, trace metals, and oxidation products that could taint final esters. Triol (trimethylolpropane) must arrive distilled and filtered, with sub-ppm water content and low color. Batch certifications track free acid number, saponification value, and moisture—off-spec inputs drag down performance, lead to yellowing, or cause poor shelf life. Good labs run regular checks on molecular profile by GC/MS, keeping close tabs on every precursor and additive. Molecules look simple on paper but every variable—cis/trans ratio, unsaturation, minor impurities—shifts final product behavior. Quality in, quality out: sticking to pure, fresh raw materials brings down unwanted hazards, eases formulation routines, and keeps everyone, from warehouse to end-user, safer in the long run.