(2S,3S)-(-)-Tartaric Acid: Physical Characteristics and Practical Use

What is (2S,3S)-(-)-Tartaric Acid?

Tartaric acid carries deep roots in food, pharma, and industrial use. The (2S,3S)-(-)-enantiomer stands out for its precise molecular configuration, favored for its consistent reactivity and optical rotation. This molecule comes from nature, especially grapes and other fruits, but large-scale production leans into chemical synthesis for consistent quality. Tracing through history books, winemakers have handled tartaric acid to control flavor and stability, long before chemists pulled apart the stereochemistry to distinguish the specific (2S,3S)-form. Its importance spans more than flavoring or fermentation; it’s in chelation, metal cleaning, and pharmaceutical synthesis.

Chemical Structure and Formula

Here, molecular structure matters. The (2S,3S)-(-)-tartaric acid molecule features two chiral centers. Its chemical formula: C4H6O6. The structure reveals two carboxylic acid groups and two hydroxyl groups, arranged symmetrically. Those groups give its distinctive reactivity. Chemists recognize its IUPAC name: (2S,3S)-2,3-dihydroxybutanedioic acid. The spatial arrangement means it rotates plane-polarized light to the left (levorotatory), which matters for analytical and synthesis work. Laboratories rely on that optical purity for multi-step synthesis and to ensure therapeutic products perform as expected.

Physical Properties

It looks like a white, crystalline solid straight out of a chemistry catalog. The crystals reflect light, and they are stable under dry, cool conditions. At room temperature, it does not release vapors, and it stays stable, offering a predictable shelf life for producers. Tartaric acid dissolves smoothly in water and forms a colorless solution — handy for lab titrations, for example, or beverage acidification. Its melting point hovers near 170°C. Water solubility comes in high, with figures near 133g/L at 20°C, meaning you can prep concentrated acids for food or reagent solutions quickly. Density clocks in at 1.76 g/cm3. Look for it as flakes, fine powders, granules, or pearls. Most suppliers ship it as a solid, but in technical setups, you may see pre-made solutions for industrial use. It melts clean, decomposes under strong heating, and does not give off strong smells, making it easy to handle on the bench.

Key Specifications and HS Code

Quality requirements hit on purity, optical rotation, moisture, and heavy metal content. Standard grades target ≥99.5% purity. Optical rotation falls tightly controlled at about –12° to –13°, depending on solution and temperature. Each batch must pass safety and contaminant tests: less than 10ppm arsenic, less than 2ppm lead. Moisture content stays under 0.5%. In trading, customs, and regulatory paperwork, you spot the HS Code 2918.12 for tartaric acid and salts, helping to track shipment and tariffs between countries. Accurate labeling gives safety for consumers and helps authorities watch over chemical markets. GHS labeling indicates the irritant nature and environmental notes, flagging it for users but not placing it in high hazard classes.

Physical Forms: Solid, Crystalline, Powder, and Solutions

People encounter tartaric acid as a white powder, chunky crystalline flakes, small pearls, or made-up solutions ready for processing. Food industry operators opt for fine powder or crystal for quick dissolution, especially in beverage tanks or jams. Many laboratory workers appreciate the easy measurement of flakes and pearls — less dust, more precision per scoop. Industrial scale-ups often choose bulk solids for mixing, but prepared solutions make on-the-fly dosing much easier for continuous processes. You don’t find it as a liquid under normal supply, but ready solutions line warehouse shelves for those who need an immediate, precise acidification boost.

Molecular and Material Safety

Sitting at low toxicity for humans, (2S,3S)-(-)-tartaric acid presents low acute hazard by ingestion or inhalation in the workplace, but dust or concentrated solutions will irritate mucous membranes, eyes, and skin. Proper lab gloves, goggles, and dust masks keep staff safe. Swallowing large amounts causes nausea and gastrointestinal discomfort — rare in industrial settings but known in poorly labeled food chains. Long-term environmental hazard sits low, as the molecule breaks down to CO2 and water in nature. On the other hand, its acidity can disrupt aquatic life in direct discharge. Wastewater controls and neutralization steps make a difference in protecting streams and soils around workshops or factories. Handling includes dry, cool storage in sealed containers to limit moisture pickup and clumping. Warehouses include tartaric acid in their chemical management plans and spill protocols, knowing that its powder spreads easily if dropped.

Raw Material Source and Sustainability

Most commercial tartaric acid flows out of the wine industry as a byproduct of winemaking. As grapes ferment, tartaric acid separates as crystals, which producers reclaim, purify, and refine for industrial use. Synthetic versions cover demand spikes or when grape-derived product runs short. Sustainability marks a hot spot. Fermentation and extraction from natural sources keeps the carbon footprint low, especially when waste byproducts feed into soil conditioners or animal feed. Large chemical plants that produce the synthetic version monitor emissions, solvent recovery, and energy use, aiming to cut environmental impacts for green labeling. End-users keep an eye on product traceability, auditing supply chains so materials stay compliant for pharmaceuticals and food additives.

Industry Use and Outlook

Everyday uses circle back to its performance in acidifying soft drinks and confectionery — the bite in sour candies, the tang in sodas, the shelf stability of jams. Pharmacies include tartaric acid to improve taste and stability of oral medications, especially in effervescent forms. Cleaning agents and textile processors count on its chelating powers to clear metal buildups. Lab chemists turn to it for precise control in reactions needing a specific chiral environment, since so many biological molecules respond to handedness. Discussions about safe use and waste handling remind industries to look after workers and the environment. Better personal protective equipment, engineering controls, and straightforward employee training all cut down on chemical injuries, boost productivity, and keep public trust high. Tartaric acid may sound niche to some, but it remains vital across industries — from vineyard to cosmetic lab, from metal works to the family kitchen.