Material Safety Data Sheet for Sodium Tartrate Dibasic Dihydrate

Identification

Product Name: Sodium Tartrate Dibasic Dihydrate
Synonyms: Disodium tartrate dihydrate; Rochelle salt
Chemical Formula: C4H4Na2O6·2H2O
CAS Number: 6106-24-7
Recommended Use: Laboratory reagent, food additive, buffer solution component
Supplier Name: Manufacturer, distributor, or chemical supplier's address and contact information provided on company label
Emergency Phone: Number reachable 24/7, usually staffed by qualified personnel familiar with sodium tartrate hazards

Hazard Identification

Classification: Not classified as hazardous under GHS criteria for pure substances
Label Elements: No pictogram, no specific hazard statement for non-hazardous classification
Potential Health Effects: Mild irritation to eyes and skin may occur after contact; low acute toxicity; may lead to gastrointestinal upset if swallowed in significant quantity
Environmental Hazards: Generally not hazardous to aquatic or terrestrial life in dilute concentrations
Signal Word: None required
Hazard Statements: May cause mild eye or skin irritation; precaution advised in handling bulk or powdered forms
Precautionary Statements: Avoid breathing dust; wash hands after handling; avoid unnecessary exposure especially with open wounds

Composition / Information on Ingredients

Chemical: Sodium Tartrate Dibasic Dihydrate
CAS Number: 6106-24-7
Percentage: 98–100% active ingredient
Impurities: Trace salts or hydrated forms may be present in technical grades; food-grade and reagent-grade usually contain little to no impurities

First Aid Measures

After Inhalation: Move patient to fresh air; seek medical attention if coughing or shortness of breath develops or lingers
After Skin Contact: Wash with soap and water; remove contaminated clothing; seek medical care if redness or irritation persists
After Eye Contact: Rinse with water for several minutes, lifting eyelids to ensure washing under the lids; contact healthcare professional if irritation does not resolve
After Ingestion: Rinse mouth; drink water to dilute chemical; do not induce vomiting unless directed by medical personnel; seek medical help for persistent stomach upset

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical, foam, or carbon dioxide can be used to control fire
Unsuitable Extinguishing Media: None known for this material
Hazardous Combustion Products: May release sodium oxides, carbon dioxide, and carbon monoxide if burned in fire
Special Protective Equipment: Wear full protective clothing and self-contained breathing apparatus when responding to large chemical fires
Fire & Explosion Hazards: Substance is not flammable or explosive but decomposition may release irritating gases in confined spaces

Accidental Release Measures

Personal Precautions: Wear appropriate chemical-resistant gloves, goggles, and lab coat or uniform
Environmental Precautions: Prevent entry to waterways, sewers, or drains; avoid spreading dust
Methods for Cleanup: Sweep up material without generating dust; collect in suitable, labeled container for reuse or disposal; clean spill area with water to remove residue

Handling and Storage

Safe Handling: Avoid inhaling dust by working with powders in well-ventilated area or under fume hood; keep containers tightly closed when not in use; use clean scoops or spatulas when removing material from container
Storage Requirements: Store in cool, dry, well-ventilated area; avoid humidity and direct sunlight; keep away from incompatible substances, especially strong acids or oxidizers
Incompatibilities: Mixing with strong acids may liberate carbon dioxide; mixing with oxidizing agents may cause reactions
Package Integrity: Use containers made of materials resistant to mild alkaline substances; properly label all containers before storage

Exposure Controls and Personal Protection

Engineering Controls: Use local exhaust ventilation or lab fume hood when generating or handling dust
Personal Protective Equipment: Wear chemical-resistant gloves (like nitrile or PVC), safety glasses with side shields, and lab coat; use respiratory protection (dust mask or respirator) if dust generation expected above safe exposure levels
Exposure Limits: No established occupational exposure limits for sodium tartrate as set by OSHA, ACGIH, or NIOSH
Hygiene Measures: Avoid eating, drinking, or smoking in work area; wash thoroughly with soap and water after handling; remove contaminated clothing before leaving work area

Physical and Chemical Properties

Appearance: White crystalline powder or granules
Odor: Odorless
Melting Point: Decomposes above 170°C (338°F)
Boiling Point: Not applicable, substance decomposes before boiling
Solubility: Freely soluble in water; insoluble in most organic solvents such as ethanol or ether
Relative Density: About 1.79 g/cm³
pH (1% Solution): 7–9
Molecular Weight: 230.08 g/mol
Other Properties: Stable under recommended storage and handling conditions; effloresces in open air; hygroscopic if exposed to high humidity

Stability and Reactivity

Chemical Stability: Remains stable under ordinary conditions of use and storage
Reactivity: Reacts with strong acids to release carbon dioxide; may react with oxidizing agents and form new products
Hazardous Decomposition Products: May form sodium oxides, carbon monoxide, carbon dioxide under high temperature or fire
Polymerization: Will not undergo hazardous polymerization
Conditions to Avoid: Moisture, extreme heat, direct exposure to strong acids or oxidizers

Toxicological Information

Acute Toxicity: Oral LD50 in rats reported greater than 5,000 mg/kg indicating low acute toxicity
Skin and Eye Irritation: May cause mild irritation on contact; not considered a skin sensitizer
Chronic Effects: Not known to cause carcinogenic, mutagenic, or reproductive toxicity effects per available evidence
Additional Data: No evidence of organ damage or cumulative toxicity with normal workplace exposure; sodium tartrate is used in food processing in low concentrations; ingestion of large amounts can lead to gastrointestinal effects like diarrhea or discomfort

Ecological Information

Ecotoxicity: No significant adverse effects noted in aquatic and terrestrial environments when present at typical environmental concentrations
Persistence and Degradability: Compound is biodegradable under natural conditions; does not bioaccumulate
Mobility: Soluble in water, can migrate through soil; unlikely to persist in environment under normal conditions
Other Adverse Effects: No data indicating chronic ecological risk; intended for use in applications with low environmental discharge potential

Disposal Considerations

Disposal Methods: Collect waste material in sealed container; dispose of at approved chemical or hazardous waste facility; follow local, regional, national, and international waste regulations
Contaminated Packaging: Rinse and recycle if possible; otherwise, treat container as hazardous material

Transport Information

UN Number: Not regulated as hazardous for transport
Proper Shipping Name: Not regulated; may be called "Non-hazardous chemical" or "Sodium Tartrate Dibasic Dihydrate" on shipping papers
Hazard Class: None assigned by transport authorities
Packing Group: Not applicable
Environmental Hazards: Not considered marine pollutant
Transport Precautions: Keep containers tightly closed, away from incompatible materials, and protect from moisture during transport

Regulatory Information

USA TSCA Status: Listed on Toxic Substances Control Act (TSCA) inventory
Food Additive Info: Recognized as safe for specific food uses by FDA when used as directed
EU Regulation: Listed under EINECS, not classified as dangerous under current EU legislation
SARA Title III: Not listed under Section 302, 313, or 311/312 hazard categories
Other Regional Inventories: Listed on Canadian DSL/NDSL, Australian AICS, Japanese ENCS, and other major chemical inventories
Workplace Labeling: Container labeling required in accordance with OSHA Hazard Communication Standard or respective local workplace safety law