Product Name: Selenium D-Gluconate
Chemical Formula: C12H22O14Se
CAS Number: 1205-79-2
Synonyms: D-Gluconic acid, selenium salt; Selenium Gluconate
Recommended Use: Nutritional supplement ingredient, food fortification, pharmaceutical applications
Supplier Details: Name, address, and emergency contact provided by manufacturer upon requisition
Manufacturer: Available upon request through the supply chain network
Emergency Telephone: Local emergency services number
GHS Classification: Acute toxicity (oral): Category 3; Skin irritation: Category 2; Eye irritation: Category 2A
Label Elements: Signal word: Danger; Hazard pictograms: Skull and crossbones, exclamation mark
Hazard Statements: Toxic if swallowed; Causes skin irritation; Causes serious eye irritation
Precautionary Statements: Do not eat, drink or smoke when using product; Wash thoroughly after handling; Wear protective gloves, protective clothing, eye protection, and face protection; IF SWALLOWED: Call a POISON CENTER/doctor; IF ON SKIN: Wash with plenty of water; IF IN EYES: Rinse cautiously with water for several minutes
Routes of Exposure: Ingestion, dermal contact, eye contact, inhalation (dust)
Chemical Identity: Selenium D-Gluconate
EC Number: 214-890-6
Concentration: 98-100% by weight
Impurities: Trace inorganic salts (not exceeding relevant thresholds)
Additives: None intentionally added
General Advice: Obtain medical attention if symptoms occur or persist.
If Inhaled: Move to fresh air, keep at rest in a position comfortable for breathing, seek medical attention for persistent discomfort.
If On Skin: Remove contaminated clothing, rinse skin immediately with running water for at least 15 minutes, seek medical attention if skin irritation or rash develops.
If In Eyes: Flush eyes with plenty of water for at least 15 minutes, lifting eyelids occasionally, remove contact lenses if present and easy to do, seek medical attention.
If Swallowed: Rinse mouth with water, do not induce vomiting, call poison control center or physician immediately.
Suitable Extinguishing Media: Water spray, foam, dry chemical powder, carbon dioxide (CO2)
Specific Hazards Arising: May emit selenium oxides and carbon oxides under fire conditions
Special Protective Equipment: Firefighters wear self-contained breathing apparatus and full protective gear
Advice for Firefighters: Approach fire from upwind to avoid hazardous vapors and thermal decomposition products
Explosion Data: Not sensitive to mechanical impact or static discharge; dust may generate explosion hazard in rare cases if accumulations reach flammable levels in confined spaces
Personal Precautions: Wear gloves, eye protection, dust mask; prevent contact with skin and eyes; ensure adequate ventilation
Environmental Precautions: Prevent runoff into surface water, soil, and the sewage system; notify authorities if larger spills cannot be contained
Cleanup Methods: Avoid raising dust, sweep up material and place in a clearly labelled waste container for proper disposal, wash area with water and detergent to remove residues, avoid release to the environment
Handling: Avoid ingestion, inhalation, direct contact with eyes, skin, or clothing; keep away from food, drink, and animal feeding stuffs; wear recommended personal protective equipment
Storage: Store in tightly sealed container in a cool, dry, well-ventilated location; keep away from direct sunlight, incompatible materials, excessive heat, acids, and oxidizers; segregate from food and drink products
Exposure Limits: OSHA PEL (total selenium): 0.2 mg/m3 TWA; ACGIH TLV: 0.2 mg/m3 TWA for selenium compounds
Engineering Controls: Local exhaust ventilation, eyewash stations, safety showers
Personal Protective Equipment: Gloves, lab coat, safety goggles, face shield, dust mask or NIOSH-approved respirator (for dusty conditions)
Hygiene Measures: Wash hands, forearms, and face after handling, before eating, and after removing personal protective equipment; change contaminated clothing promptly
Appearance: White to off-white crystalline powder
Odor: Odorless
Odor Threshold: Not applicable
pH (1% solution): 5.5 – 7.5
Melting Point/Range: Decomposes before melting
Boiling Point: Not applicable
Flash Point: Not flammable
Evaporation Rate: Not applicable
Upper/Lower Flammability: Not limiting
Vapor Pressure: Not applicable
Vapor Density: Not applicable
Relative Density: 1.8 - 2.2 (g/cm3)
Solubility: Soluble in water
Partition Coefficient: Data not available
Auto-ignition Temperature: Not self-igniting
Decomposition Temperature: Above 180°C
Viscosity: Not applicable
Chemical Stability: Remains stable under recommended storage and handling conditions
Possibility of Hazardous Reactions: Does not polymerize or form hazardous reactants under normal conditions
Conditions to Avoid: Exposure to excessive heat, moisture, direct sunlight, and incompatibles (strong oxidizers, acids)
Incompatible Materials: Strong acids, strong oxidizing agents, reducing agents
Hazardous Decomposition Products: Emits toxic fumes of selenium oxides and carbon oxides during combustion or thermal decomposition
Acute Toxicity: Oral LD50 (rat): 7–15 mg/kg (as selenium); potential for toxic effects at low doses
Chronic Toxicity: Long-term or repeated exposure can impact liver, kidneys, gastrointestinal tract, and central nervous system
Skin Corrosion/Irritation: Causes irritation with redness or rash upon contact
Serious Eye Damage/Irritation: Causes eye irritation; redness, pain, or damage with direct exposure
Respiratory or Skin Sensitization: Prolonged contact may trigger allergic reactions in sensitive individuals
Carcinogenicity: Not classified as a carcinogen by NTP, IARC, OSHA
Reproductive Toxicity: Overexposure to selenium compounds has been linked to reproductive risks in animal studies; insufficient evidence in humans
Mutagenicity: No data available for mutagenic effects in standard tests
Ecotoxicity: Highly toxic to aquatic organisms; potential to bioaccumulate and impact aquatic food chains
Persistence and Degradability: Not readily biodegradable; selenium compounds persist and may transform to other selenium species through microbial action
Bioaccumulative Potential: Selenium accumulates through food webs and can become toxic at higher trophic levels
Mobility in Soil: Moderate potential; selenium salts can leach through soil and contaminate groundwater
Other Adverse Effects: Discharge to the environment must be prevented; follow local authority guidelines
Disposal Methods: Treat as hazardous waste; incinerate in authorized facility or treat chemically according to local, regional, and national regulations
Contaminated Packaging: Dispose of as unused product; do not reuse containers unless thoroughly cleaned and inspected
Disposal Precautions: Avoid discharge to the environment; notify regulatory authorities in the event of significant spill or contamination incident
UN Number: 3283 (Selenium compound, not otherwise specified)
UN Proper Shipping Name: Selenium compound, n.o.s.
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: II
Labels: Toxic
Environmental Hazards: Marine pollutant; highly toxic to aquatic life
Special Precautions: Handle following guidelines for toxic substances; emergency response information must be readily available
Regulatory Requirements: Compliance with country and international transport regulations is mandatory
OSHA Status: Regulated as a hazardous chemical, subject to Hazard Communication Standard
SARA 313: Selenium compounds appear on the list of toxic chemicals subject to reporting requirements
TSCA Status: All components listed on the Toxic Substances Control Act inventory
EU Regulations: Registered under REACH; classified as hazardous according to CLP/GHS regulations
WHMIS Classification (Canada): D1B (Toxic Material), D2B (Other Toxic Effects)
Labeling for Consumer Use: Must include warning regarding selenium toxicity and recommended safe handling instructions
Other regulatory considerations: Local and regional regulations on environmental discharge, food and supplement safety, and workplace exposure limits apply
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