Material Safety Data Sheet for Di(Propylene Glycol) Methyl Ether Acetate

Identification

Product Name: Di(Propylene Glycol) Methyl Ether Acetate
Synonyms: Propylene glycol methyl ether acetate, DPM Acetate
Chemical Formula: C10H20O4
CAS Number: 88917-22-0
Intended Use: Solvent for coatings, inks, adhesives, chemical formulations
Supplier: Name, address, and emergency contact of manufacturer or distributor provided on supplier packaging
Emergency Phone Number: Accessible 24-hour contact from supplier’s safety program

Hazard Identification

Classification: Flammable liquid category 4, Eye irritation category 2A, Specific target organ toxicity (single exposure) category 3
Hazard Statements: May cause eye irritation; May cause drowsiness and dizziness; Combustible liquid
Signal Word: Warning
Pictograms: Exclamation mark
Precautionary Statements: Avoid breathing vapor; Use only outdoors or in well-ventilated area; Wear eye protection; Keep away from heat, sparks, open flame
Symptoms: Eye redness, headache, somnolence, respiratory discomfort at high concentrations

Composition / Information on Ingredients

Chemical Name: Di(Propylene Glycol) Methyl Ether Acetate
Concentration: ≥ 98% by weight
Other Components: Water (<0.5%), Organic impurities (<1.0%)
Impurities Contributing to Hazard: None above threshold limits

First Aid Measures

Inhalation: Move to fresh air, monitor breathing, seek medical advice if effects persist
Skin Contact: Remove contaminated clothing, wash skin with mild soap and water, seek advice for persistent irritation
Eye Contact: Rinse cautiously with water for 15 minutes, remove contact lenses if present and easy to do, obtain medical attention for ongoing irritation
Ingestion: Do not induce vomiting, rinse mouth thoroughly, get immediate medical advice
Most Important Symptoms: Respiratory irritation, drowsiness, nausea, eye or skin redness
Advice to Physician: Treat symptomatically, monitor for respiratory or neurologic complications

Fire-Fighting Measures

Extinguishing Media: Use alcohol-resistant foam, dry chemical, water spray, or carbon dioxide
Unsuitable Media: Do not use direct water jet on product to prevent spread of fire
Hazards from Combustion Products: Carbon monoxide, carbon dioxide, organic vapors
Protective Equipment: Wear self-contained breathing apparatus and full protective suit
Special Firefighting Procedures: Cool closed containers with water spray to prevent pressure buildup
Fire/Explosion Risk: Vapors may form explosive mixtures with air in confined spaces

Accidental Release Measures

Personal Precautions: Ventilate area, eliminate ignition sources, wear appropriate protective clothing and gloves
Environmental Precautions: Prevent product from entering drains, waterways, and soil; contain spillage using sand, earth or other inert material
Spill Clean-Up: Absorb on inert absorbent, collect and place in suitable closed containers for disposal
Decontamination Methods: Wash spill site with water and detergent after material pickup
Notification: Report large releases to regulatory authorities according to local requirements

Handling and Storage

Handling: Use only in well-ventilated locations, avoid inhalation and contact with skin or eyes; ground and bond containers when transferring liquid, keep containers tightly closed
Storage: Store in original containers in cool, dry, well-ventilated area away from incompatible materials including strong oxidizers, acids and bases
Safe Storage Temperatures: Keep below 35°C; avoid freezing
Transfer Procedures: Use non-sparking tools, proper grounding
Storage Limitations: Do not store near food, beverages or animal feed

Exposure Controls and Personal Protection

Occupational Exposure Limits: No ACGIH TLV or OSHA PEL established for this substance; minimize exposure as per good industrial hygiene practices
Engineering Controls: Use local exhaust ventilation at points of emission and general area ventilation to minimize vapor accumulation
Eye Protection: Safety goggles meeting EN 166 or equivalent
Skin Protection: Chemically resistant gloves (nitrile, neoprene), protective clothing
Respiratory Protection: OSHA-approved respirator if ventilation is inadequate or exposure limits may be exceeded
Hygiene Measures: Wash hands before breaks and after handling; take off contaminated clothing and wash before reuse

Physical and Chemical Properties

Appearance: Clear, colorless to faint yellow liquid
Odor: Faint, pleasant, ether-like
Odor Threshold: Data not available
pH: Not applicable (non-aqueous)
Melting/Freezing Point: -65°C
Boiling Point Range: 245-250°C
Flash Point: 96°C (closed cup)
Evaporation Rate: Slower than butyl acetate
Flammability: Combustible liquid
Vapor Pressure: 0.03 mmHg at 20°C
Vapor Density (Air=1): 6.12
Relative Density: 1.01 at 20°C
Solubility: Miscible with water and common organic solvents
Partition Coefficient (Log Kow): 0.5 – 1.0
Auto-Ignition Temperature: 307°C
Decomposition Temperature: Data not available
Viscosity: 2.4 mPa·s at 25°C

Stability and Reactivity

Chemical Stability: Stable under normal conditions
Reactivity: No dangerous reactions expected under normal use
Possible Hazardous Reactions: Exothermic reaction with strong oxidizing agents
Conditions to Avoid: Heat, sparks, open flame, excessive temperatures above storage recommendations
Incompatible Materials: Strong acids, alkalis, oxidizers
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, organic compounds under fire conditions

Toxicological Information

Acute Toxicity: Oral LD50 (rat) > 4000 mg/kg, Dermal LD50 (rabbit) > 2000 mg/kg
Skin Corrosion/Irritation: Mild irritation possible on prolonged exposure
Serious Eye Damage/Irritation: Causes moderate and reversible eye irritation
Respiratory Sensitization: Not classified as a respiratory sensitizer
Skin Sensitization: Not expected to cause sensitization
Reproductive Toxicity: Studies show no evidence of developmental effects at non-toxic doses
Carcinogenicity: No components classified as carcinogenic by IARC, NTP, OSHA
Specific Target Organ Effects: Central nervous system depression possible at high vapor concentrations
Long-term Effects: No evidence of chronic health effects from available data

Ecological Information

Aquatic Toxicity: LC50 (fish, 96 hr) > 100 mg/L; EC50 (daphnia, 48 hr) > 100 mg/L; EC50 (algae) > 100 mg/L
Mobility: High mobility in soil due to good solubility in water
Persistence and Degradability: Readily biodegradable under aerobic conditions
Bioaccumulation Potential: Low, Log Kow below threshold for concern
Other Adverse Effects: Not classified as hazardous to the environment

Disposal Considerations

Waste Treatment Methods: Collect and recover or dispose of at an authorized hazardous waste facility
Container Disposal: Empty containers may retain product residue, dispose of in accordance with local regulations
Sewage Disposal: Avoid release to sewer systems
Recycling Recommendations: Recycle product when feasible; avoid landfill where possible
Disposal Regulations: Follow national, regional, and local regulations regarding hazardous chemical disposal
Special Precautions: Do not cut or weld empty containers

Transport Information

UN Number: Not regulated for transport under most international regulations
Proper Shipping Name: Not applicable
Transport Hazard Class: Not classified as a dangerous good
Packing Group: Not assigned
Environmental Hazards: Not classified as marine pollutant
Special Precautions for User: During large transport quantities, follow company-specific best practices for containment
Bulk Transport According to Annex II of MARPOL 73/78: Not subject to regulations

Regulatory Information

OSHA Status: Not hazardous under OSHA Hazard Communication Standard
TSCA Inventory: Listed
EINECS/ELINCS Number: 500-427-9
REACH Status: Registered and compliant
SARA Title III: Not subject to reporting under SARA Section 313
California Proposition 65: Product does not contain chemicals subject to Proposition 65 warnings
International Inventories: Listed on major chemical inventories including DSL, AICS, ENCS, PICCS, IECSC, NZIoC
Labeling Information: GHS-compliant labeling on packaging, includes hazard pictogram, signal word, and precautionary statements
Other Applicable Regulations: Complies with applicable chemical safety laws in country of sale