Material Safety Data Sheet: Dipropylene Glycol Butyl Ether

Identification

Product Name: Dipropylene Glycol Butyl Ether
Chemical Formula: C10H22O3
CAS Number: 29911-28-2
Synonyms: DPNB, Butoxydipropylene Glycol
Application: Used in cleaners, paints, inks, coatings, and solvents
Manufacturer Contact: Refer to supplier section on product label
Emergency Telephone Number: Listed on shipping papers and product label
Recommended Use: Cleaning formulations, industrial coatings, printing applications, chemical manufacturing

Hazard Identification

GHS Classification: Eye irritation – Category 2A, Skin irritation – Category 3
Signal Word: Warning
Hazard Statements: Causes serious eye irritation, may cause mild skin irritation, may cause respiratory irritation
Pictogram: Exclamation mark
Precautionary Statements: Avoid inhalation, wash skin after handling, use eye protection, use gloves
Potential Health Effects: Prolonged exposure may irritate eyes and skin, inhaling vapor may cause headache or dizziness, ingestion may upset stomach and cause nausea
Environmental Hazards: Product can be harmful to aquatic life with long lasting effects if released in large quantities

Composition / Information on Ingredients

Chemical Identity: Dipropylene Glycol Butyl Ether
Concentration: >98% by weight
Impurities: May contain trace levels of dipropylene glycol methyl ether or unreacted propylene glycol derivatives
CAS Number: 29911-28-2
EC Number: 249-951-5
Molecular Weight: 190.28 g/mol

First Aid Measures

Eye Contact: Rinse eyes with water for at least 15 minutes, remove contact lenses, seek medical attention if irritation persists
Skin Contact: Wash affected area with soap and water, remove contaminated clothing, get medical help if irritation develops
Inhalation: Move affected person to fresh air, support breathing if needed, consult a physician if symptoms continue
Ingestion: Rinse mouth, give water to drink if conscious, never induce vomiting, seek medical advice immediately
Note for Physicians: Treat symptomatically, monitor respiratory and cardiovascular function

Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray, foam, dry chemical, or carbon dioxide
Specific Hazards: Vapors heavier than air, may form explosive mixtures with air at higher temperatures, combustion produces carbon monoxide and dioxide
Protective Equipment for Firefighters: Wear self-contained breathing apparatus, chemical resistant clothing
Special Procedures: Cool containers exposed to fire with water spray, control runoff to prevent entry into sewers or waterways
Explosion Data: Vapors may ignite rapidly if exposed to sparks or flames

Accidental Release Measures

Personal Precautions: Evacuate area, ventilate, avoid contact with skin, eyes, and clothing, use gloves and goggles
Environmental Precautions: Prevent runoff into drains, watercourses, and soil by diking
Methods for Clean-Up: Contain and collect spill with inert absorbent materials like sand, place in chemical waste container
Reference to Other Sections: Refer to exposure controls, personal protection, and disposal information for handling contaminated material

Handling and Storage

Safe Handling: Avoid inhaling vapors, use only in well-ventilated areas, prevent contact with skin and eyes, wash hands after use
Storage Requirements: Store in tightly closed containers, keep in a cool, dry, well-ventilated location away from sources of ignition and incompatible materials
Incompatible Materials: Strong acids, strong oxidizing agents, reactive metals
Other Precautions: Provide eye wash stations and safety showers near usage areas, label containers clearly, minimize splashing and vapor release by keeping containers closed

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established ACGIH TLV or OSHA PEL for dipropylene glycol butyl ether
Engineering Controls: Use local exhaust ventilation, maintain eyewash stations, consider explosion-proof equipment in areas with vapor formation
Personal Protective Equipment: Wear chemical-resistant gloves (nitrile or neoprene), splash-proof safety goggles, long-sleeved protective clothing
Respiratory Protection: Use approved respirator if vapor or mist concentrations exceed recommended guidelines
Hygiene Measures: Remove contaminated clothing immediately, wash thoroughly after handling, do not eat or smoke while using this product

Physical and Chemical Properties

Appearance: Colorless liquid
Odor: Faint, mild ether-like odor
Odor Threshold: Not determined
pH: Not applicable
Melting/Freezing Point: Approximately -80°C
Boiling Point and Range: 230°C – 250°C
Flash Point: 93°C (closed cup)
Evaporation Rate: Slower than water
Flammability: Combustible liquid
Explosion Limits: Not available
Vapor Pressure: 0.01 mmHg @ 20°C
Vapor Density: 6.5 (air = 1)
Solubility: Miscible with water and most organic solvents
Partition Coefficient (log Kow): Approx. 0.56
Auto-Ignition Temperature: Above 200°C
Decomposition Temperature: Not determined
Viscosity: 6.3 mPa.s @ 20°C

Stability and Reactivity

Chemical Stability: Stable under standard conditions and storage guidelines
Reactivity: Not reactive under normal handling, can react with oxidizers
Possibility of Hazardous Reactions: May form peroxides under prolonged exposure to air
Incompatible Materials: Avoid strong acids, bases, and oxidizing agents
Hazardous Decomposition Products: Produces carbon monoxide, carbon dioxide, and other irritating fumes upon combustion or decomposition
Conditions to Avoid: Keep away from open flames, hot surfaces, sparks, static discharge

Toxicological Information

Routes of Exposure: Inhalation, skin contact, ingestion, eye contact
Acute Toxicity: Oral LD50 (rat) > 2000 mg/kg, Dermal LD50 (rabbit) > 2000 mg/kg
Skin Corrosion/Irritation: May cause mild irritation following prolonged or repeated contact
Serious Eye Damage/Irritation: Causes eye irritation, redness, tearing can occur
Respiratory Effects: Inhalation of vapor can produce dizziness, headache, and drowsiness at high concentrations
Chronic Effects: No significant data to support chronic toxicity, repeated or prolonged contact increases risk of dermatitis
Mutagenicity/Carcinogenicity/Reproductive Toxicity: No data show mutagenic, carcinogenic, or reproductive effects in standard animal testing

Ecological Information

Ecotoxicity: Slightly toxic to aquatic life, EC50 (Daphnia magna) estimated at >1000 mg/L, LC50 (Fish, 96-hr) >1000 mg/L
Persistence and Degradability: Expected to be readily biodegradable, will not persist in soil or water
Bioaccumulative Potential: Low based on log Kow value
Mobility in Soil: High, likely to move through soil to groundwater
Other Adverse Effects: Avoid contamination of natural water sources through improper disposal or large releases

Disposal Considerations

Waste Disposal Methods: Do not allow into drains, water systems, or soil; incinerate in approved facility or dispose through licensed hazardous waste contractor
Container Disposal: Triple rinse containers before recycling; containers may retain product residues—follow federal, state, and local regulations for hazardous waste chemicals
Recommended Disposal: Consult environmental authority or waste contractor for compliance with national and local regulations; avoid landfill for large quantities

Transport Information

UN Number: Not classified as dangerous goods according to UN Model Regulations
UN Proper Shipping Name: Dipropylene Glycol Butyl Ether
Transport Hazard Class: Not classified
Packing Group: Not applicable
Marine Pollutant: No
Special Precautions for Transport: Secure containers well, avoid transport with incompatible materials, check specific carrier requirements

Regulatory Information

OSHA Status: Not listed as hazardous under OSHA Hazard Communication Standard
TSCA Inventory: Listed
REACH Registration: Registered substance in EU, check compliance for import and export
SARA Title III Sections 302/304: Not listed
SARA Title III Section 313: Not subject to reporting
WHMIS Classification (Canada): D2B (toxic materials causing other effects)
California Proposition 65: Not listed
Other applicable regulations: Local and international transport and safety rules may apply; consult local environmental authority for final use determinations