MSDS for Potassium Tartrates

Identification

Product Name: Potassium Tartrates
Common Names: Dipotassium tartrate, Potassium bitartrate (cream of tartar)
Chemical Formula: K2C4H4O6 or KC4H5O6
CAS Numbers: 868-14-4 (Dipotassium tartrate), 868-06-4 (Potassium bitartrate)
Recommended Uses: Food additive, laboratory reagent, pharmaceutical ingredient, stabilizer in baked goods, component in metallurgical fluxes
Supplier Information: Manufacturers’ and distributors’ contact details including phone numbers, addresses, emergency contact lines

Hazard Identification

Classifications: Potassium tartrates generally fall under non-hazardous materials for ordinary handling, but larger quantities or dust inhalation can cause mild irritation.
GHS Classification: Not classified as dangerous.
Pictogram: No symbol required under GHS.
Hazard Statements: May cause eye or skin irritation. Dust or powder can irritate the respiratory system.
Precautionary Statements: Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Use with adequate ventilation. Keep away from food and drink.

Composition / Information on Ingredients

Chemical Name: Dipotassium tartrate or Potassium bitartrate
Percentage: Typically >99% pure
Impurities: Small traces of sodium tartrate, water, organic contaminants (often below reporting threshold)
Molecular Weight: Dipotassium tartrate: 226.27 g/mol; Potassium bitartrate: 188.18 g/mol

First Aid Measures

Inhalation: Move the person to fresh air. If coughing or difficulty breathing develops, seek medical attention. Rinse mouth and clear throat of any powder.
Skin Contact: Remove contaminated clothing. Wash affected area with soap and water. If irritation persists, contact a physician.
Eye Contact: Rinse eyes immediately with plenty of water for at least 15 minutes. Keep eyelids open and away from eyeball. Seek medical attention for persistent irritation.
Ingestion: Rinse mouth. Drink water to dilute. Never induce vomiting unless directed by medical personnel. If a substantial quantity is swallowed, get medical advice.

Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray or fog, dry chemical, foam, or carbon dioxide. Avoid direct water jets.
Special Hazards: During combustion, potassium tartrates may produce carbon oxides and potassium oxides.
Protective Equipment: Wear full protective gear, including NIOSH-approved self-contained breathing apparatus, fire-resistant clothing, goggles, and gloves.
Advice for Firefighters: Approach from upwind. Keep containers cool. Avoid inhaling combustion fumes.

Accidental Release Measures

Personal Precautions: Wear safeguards like gloves, goggles, and a dust mask. Ventilate area if powder is airborne. Limit entry, especially by unprotected personnel.
Environmental Precautions: Keep material out of drains and watercourses. Sweep or scoop up undamaged product to minimize dust.
Methods for Clean-Up: Collect and containerize the spill using inert, clean-up materials. Remove residue with water. Dispose according to local regulations.

Handling and Storage

Safe Handling: Avoid generating dust. Handle in ventilated areas. Wash hands thoroughly after handling. Avoid contact with skin, eyes, and clothing. Do not eat, drink, or smoke near the material.
Storage Conditions: Store in a cool, dry, and well-ventilated area. Use tightly closed, labeled containers made of compatible material (polyethylene, glass). Keep away from strong acids or oxidizers. Protect from moisture, direct sunlight, and extreme temperatures.

Exposure Controls and Personal Protection

Exposure Limits: No established occupational exposure limits for potassium tartrates.
Engineering Controls: Use local exhaust ventilation to keep airborne concentrations below recommended limits. Provide eyewash stations and safety showers.
Personal Protective Equipment: Chemical-resistant gloves, safety goggles, dust mask or respirator if airborne dust is present, lab coat or apron. Good laboratory hygiene prevents accidental exposure.

Physical and Chemical Properties

Appearance: White, odorless crystalline or powdery solid
Odor: Odorless
pH: Slightly acidic to neutral in solution (pH ~3.5–6.0 depending on form)
Melting Point: Decomposes above 230°C (Dipotassium tartrate), 168–170°C (Potassium bitartrate, decomposes)
Boiling Point: Not applicable; decomposes before boiling
Solubility: Slightly soluble in cold water, more soluble in warm water
Vapor Pressure: Negligible at room temperature
Density: 1.98 g/cm³ (Potassium bitartrate), 2.0 g/cm³ (Dipotassium tartrate)

Stability and Reactivity

Chemical Stability: Stable under recommended storage and handling conditions.
Reactivity: Non-reactive under normal use; may react with strong acids to produce tartaric acid and release carbon dioxide
Incompatible Materials: Strong oxidizing agents, concentrated acids, strong bases
Hazardous Decomposition Products: Releases carbon oxides and potassium oxide if heated to decomposition
Risk of Polymerization: Does not occur

Toxicological Information

Acute Toxicity: Low toxicity via oral, dermal, or inhalation routes. Oral LD50 in rats: >2000 mg/kg
Potential Health Effects: May irritate eyes, skin, and mucous membranes. Large ingestions may cause stomach discomfort, nausea, or diarrhea.
Carcinogenicity: Not classified as a carcinogen by IARC, NTP, or OSHA
Chronic Effects: No chronic health effects under normal handling
Sensitization: Not expected to cause allergic reactions

Ecological Information

Ecotoxicity: Low expected environmental hazard. Unlikely to bioaccumulate. High concentrations in water may temporarily disturb aquatic ecosystems.
Persistence and Degradability: Biodegradable by soil and water microorganisms.
Mobility: Solid, water-soluble — may move through soil into groundwater if spilled in large amounts.
Bioaccumulation: Not expected due to low octanol-water partition coefficient.

Disposal Considerations

Waste Treatment Methods: Dispose of non-recyclable stock through a licensed chemical waste contractor. Store residue in tightly sealed, labeled containers.
Disposal of Packaging: Rinse empty containers. Dispose of via municipal waste, recycling, or hazardous-waste procedures, according to local regulation.
Special Precautions: Prevent release to sewage and natural waterways.

Transport Information

UN Number: Not regulated for transport (non-hazardous material)
Transport Hazard Class: Not applicable
Packing Group: Not applicable
Labels: None required
Shipping Name: Potassium tartrates
Environmental Hazards: Not classified as a marine pollutant. Avoid large releases to water during transit.

Regulatory Information

Inventory Listings: Registered in TSCA (US), EINECS/ELINCS (EU), DSL (Canada), ENCS (Japan)
Regulatory Status: Not classified as hazardous under OSHA, EU-CLP, or GHS guidelines. FDA-approved as a food additive under specified limits.
Restriction Notes: Use in food applications limited by national food safety agencies for maximum purity and allowable daily intake.
Other Regulations: No SARA Title III, CERCLA, or RCRA hazardous listing. Follow worker safety laws and general chemical handling regulations.