Material Safety Data Sheet: Polypropyleneglycol #800 Monobutyl Ether

Identification

Chemical Name: Polypropyleneglycol #800 Monobutyl Ether
Synonyms: Butoxy Polypropylene Glycol, PPG Monobutyl Ether
CAS Number: 9003-13-8
Recommended Use: Industrial solvent, chemical intermediate, component in cleaning products, surfactant base
Manufacturer: Name and address of chemical manufacturer or distributor
Emergency Contact: 24-hour emergency phone number, product information hotline

Hazard Identification

GHS Classification: Eye irritation (Category 2A), Skin irritation (Category 2), Specific target organ toxicity - single exposure (Category 3, narcotic effects)
Signal Word: Warning
Hazard Statements: Causes skin and eye irritation, may cause drowsiness or dizziness after inhalation, can be harmful if swallowed
Pictograms: Exclamation mark symbol (for irritant)
Precautionary Statements: Avoid breathing vapor, wash hands after use, wear protective gloves and eye/face protection, use only outdoors or in a well-ventilated area, do not eat, drink, or smoke when using this product

Composition / Information on Ingredients

Chemical Composition: Polypropyleneglycol monobutyl ether (~100%)
Impurities: Trace amounts of other glycol ethers, polypropylene oxide oligomers, potential residual catalysts
CAS Number: 9003-13-8
Typical Content: No major non-active ingredients present, product is sold as a pure or nearly pure substance

First Aid Measures

Inhalation: Remove affected person to fresh air, allow to rest, seek medical attention if symptoms persist or worsen, keep warm and at rest
Skin Contact: Wash skin thoroughly with soap and water, remove contaminated clothing, seek medical attention for persistent irritation, do not reuse contaminated garments before proper cleaning
Eye Contact: Rinse eyes gently with clean water for at least 15 minutes, lift eyelids for thorough rinsing, seek prompt medical attention
Ingestion: Do not induce vomiting, rinse mouth, give water only if conscious, seek immediate medical attention

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, carbon dioxide, alcohol-resistant foam, water spray for large fires
Hazardous Combustion Products: Carbon monoxide, carbon dioxide, possibly irritating or toxic vapors
Protective Equipment: Firefighters wear self-contained breathing apparatus, protective clothing to prevent contact with skin and eyes
Specific Hazards Arising from the Chemical: Product may form flammable or explosive mixtures with air at elevated temperatures, pressurized containers can rupture when exposed to fire
Advice for Firefighters: Cool exposed containers with water spray to prevent rupture, avoid inhalation of combustion products, evacuate area if necessary

Accidental Release Measures

Personal Precautions: Evacuate area, ventilate space, avoid contact with spilled product, use appropriate personal protective equipment
Environmental Precautions: Prevent entry into drains, watercourses, or soil, contain spill with absorbent materials such as sand or earth, notify authorities if product enters environment
Methods for Cleaning Up: Absorb with inert material, place in chemical waste containers, clean spill area with water and detergent, dispose of waste in accordance with local requirements
Reference to Other Sections: For exposure controls and disposal considerations, see related MSDS sections

Handling and Storage

Precautions for Safe Handling: Use only in well-ventilated areas, avoid contact with skin and eyes, wash hands and face after handling, avoid inhalation of vapors or spray, prevent formation of aerosols
Conditions for Safe Storage: Store in tightly closed containers, keep in cool, dry, well-ventilated location, protect from heat sources, incompatible materials include strong acids and bases, oxidizers
Special Packaging Requirements: Use corrosion-resistant containers, segregate away from food and drink supplies

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established occupational exposure limits for Polypropyleneglycol monobutyl ether, recommend treating as for other glycol ethers
Engineering Controls: Provide general or local exhaust ventilation to minimize vapor exposure, use closed process equipment if available
Personal Protective Equipment: Chemical-resistant gloves (nitrile, neoprene), splash-resistant safety goggles, protective clothing, use respiratory protection for high vapor concentrations, eye wash and safety shower available in work area

Physical and Chemical Properties

Physical State: Colorless to pale yellow liquid
Odor: Mild, ether-like
pH: Not available
Melting / Freezing Point: Typically below -10°C
Boiling Point: Approx. 250–300°C
Flash Point: Above 115°C (closed cup)
Vapor Pressure: Low at room temperature
Solubility: Miscible with water and common organic solvents
Density: Approximately 1.0 g/cm³ at 20°C
Viscosity: Medium to high for a glycol ether
Partition Coefficient (n-octanol/water): Not determined
Autoignition Temperature: > 350°C

Stability and Reactivity

Chemical Stability: Stable under normal conditions, decomposes at elevated temperatures
Possibility of Hazardous Reactions: Can react with strong acids, strong bases, and oxidizing agents, excessive heating or incomplete combustion can generate hazardous byproducts
Conditions to Avoid: Overheating, open flames, sources of ignition, mixing with incompatible materials
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, possible aldehydes or organic acids formed on decomposition

Toxicological Information

Routes of Exposure: Inhalation, skin contact, eye contact, ingestion
Acute Effects: Eye and skin irritation, respiratory tract irritation, headache, dizziness if inhaled in large amounts
Chronic Effects: Prolonged or repeated exposure may cause dermatitis or respiratory effects, potential effects on central nervous system
LD50/LC50: Data indicates oral LD50 (rat) likely > 2,000 mg/kg based on similar glycol ethers
Carcinogenicity: No components listed as carcinogens by IARC, NTP, OSHA
Other Effects: No evidence of mutagenicity, no known reproductive effects at typical exposures

Ecological Information

Aquatic Toxicity: Limited acute aquatic toxicity, low potential to bioaccumulate due to high solubility and biodegradability, may be toxic to aquatic organisms at high concentrations
Degradation: Product is expected to be readily biodegradable under aerobic conditions, breakdown products unlikely to persist in environment
Mobility in Soil: Product will partially adsorb to soil, most will migrate with water due to solubility
Persistence: Not expected to be persistent in natural environments
Other Environmental Hazards: Large releases may damage aquatic or terrestrial environments by oxygen demand or physical effects

Disposal Considerations

Waste Disposal: Dispose of in accordance with national, regional, and local regulations, do not pour into drains or waterways, use licensed chemical-waste disposal contractors
Container Disposal: Rinse empty containers with water, dispose of through approved recycling or disposal facilities, do not reuse chemical containers for food or drink
Special Precautions: Prevent unintentional release to the environment, label discarded materials for proper handling

Transport Information

UN Number: Not regulated for ground, air, or sea transport under most shipping regulations
Proper Shipping Name: Non-hazardous glycol ether liquid (under standard criteria)
Transport Hazard Class: Not regulated
Packing Group: Not regulated
Environmental Hazards: Not marine pollutant
Special Transport Precautions: Keep containers tightly sealed, transport in upright position to avoid leakage, ensure secondary containment for bulk shipments

Regulatory Information

Inventory Status: Listed on TSCA, ECHA, AICS, DSL chemical inventories
SARA Title III: Not subject to reporting under Sections 302, 304, 313
OSHA Hazard Communication: Classified as an irritant
WHMIS Classification: D2B (toxic, causing other effects)
Other Regulations: Ensure compliance with all specific local, state, or regional chemical safety laws governing use, handling, storage, and disposal