Product Name: Polypropylene Glycol Octyl Ether
Chemical Name: Poly(oxy-1,2-ethanediyl), alpha-octyl-omega-hydroxy-, mono ether with 1,2-propanediol
Synonyms: PPOE, PPG Octyl Ether
CAS Number: 9038-95-3
Recommended Uses: Surfactant, antifoam agent in coatings, cleaning formulations
Manufacturer Contact: Emergency phone and supplier contact information provided on packaging or demand
Contact for Technical Details: Safety officer, environmental health group of the producing company
Classification: Not classified as hazardous under GHS, but exposure precautions remain vital due to minor irritation risk
Signal Word: None required under GHS, prudent handling needed
Pictogram: None mandated for consumer use, PPE suggested for bulk use
Major Hazards: May cause eye and skin irritation, inhalation of aerosols may irritate upper respiratory tract
Precautionary Statements: Avoid direct contact with skin and eyes, ventilate workspace appropriately
Hazard Statements: Causes mild irritation on skin or eye contact; ingestion leads to stomach discomfort
Chemical Identity: Polypropylene glycol octyl ether
Common Impurities: ≤2% ethylene oxide, propylene glycol
Purity: ≥98% for technical grade product
Molecular Formula: C11H24O3 (range depends on chain length)
Key Ingredients: Main active component; trace amounts of manufacturing residuals
Inhalation: Remove person to fresh air; seek help if irritation or breathing difficulty persists
Skin Contact: Wash skin thoroughly with soap and lukewarm water; remove contaminated clothing
Eye Contact: Rinse eyes gently with plenty of water for at least 15 minutes; call a physician for persistent pain
Ingestion: Do not induce vomiting; rinse mouth; drink water; seek medical attention if symptoms develop
Notes for Healthcare Professionals: Symptomatic treatment recommended, watch for sensitization or allergic reaction
Flammability: Not classified as easily flammable, but can burn at high temperatures
Suitable Extinguishing Media: Dry chemical, foam, carbon dioxide, water spray (for large fires)
Hazardous Combustion Products: Emits carbon monoxide, carbon dioxide, and possibly aldehydes upon combustion
Protective Equipment: Full protective clothing and self-contained breathing apparatus for responders
Special Procedures: Cool exposed containers with water spray to reduce rupture risk
Personal Protection: Wear gloves, goggles, protective clothing; ensure local exhaust ventilation
Spill Response: Prevent further leakage if safe; absorb with inert dry material (e.g., sand, earth)
Waste Disposal: Collect absorbed material in appropriately labeled containers for proper disposal
Decontamination: Wash area with water and mild soap; prevent entry into drains or waterways
Environmental Precautions: Avoid uncontrolled discharge to environment; inform relevant authorities if water/waste is contaminated
Handling: Wear suitable PPE; avoid creation of aerosols or mist; use only in well-ventilated areas
Advice on Safe Use: Minimizing unnecessary exposure, sealing containers tightly after each use
Storage Conditions: Store in original container, tightly sealed, in a cool, dry, well-ventilated location
Technical Protection: Use spill containment pallets in bulk storage; keep away from incompatible materials
Specific End Uses: Only use as intended by manufacturer, avoid unintended mixing
Exposure Limits: None set by OSHA, ACGIH or NIOSH for this specific chemical
Engineering Controls: Local exhaust recommended for processes producing spray or mist
Personal Protective Equipment: Chemical-resistant gloves, goggles, apron or lab coat
Respiratory Protection: Respirator with organic vapor cartridge when adequate ventilation is not available
Hygienic Measures: Wash hands before eating, drinking or smoking; shower after high-level exposure
Appearance: Colorless to pale yellow, viscous liquid
Odor: Mild, slight ether-like aroma
pH: Neutral to slightly basic, typically 6-8 (5% solution in water)
Boiling Point Range: 250-350°C (depends on average molecular weight)
Melting/Freezing Point: Less than -20°C for most chain lengths
Flash Point: >170°C (closed cup)
Vapor Pressure: Extremely low at 20°C
Density: 0.99-1.05 g/cm3 at 20°C
Solubility: Soluble in water and most organic solvents
Partition Coefficient (n-octanol/water): Moderate potential for bioaccumulation
Viscosity: 100-150 mPa·s (25°C, depends on grade)
Chemical Stability: Stable under recommended handling and storage conditions
Hazardous Reactions: Reacts with strong oxidizers, strong acids
Decomposition Products: Produces carbon monoxide, carbon dioxide, hydrocarbons under thermal decomposition
Conditions to Avoid: High temperatures, sparks, open flames, incompatible chemicals
Polymerization: Not known to occur under normal conditions
Acute Toxicity: Low oral and dermal toxicity based on animal studies; quantitative LD50 not readily available
Irritation: Causes mild to moderate eye and skin irritation after prolonged or repeated contact
Sensitization: No confirmed evidence of skin sensitization in humans
Chronic Effects: Prolonged exposure leads to dryness, defatting of skin; no known long-term systemic toxicity
Carcinogenicity: Not listed by NTP, IARC, ACGIH, OSHA
Mutagenicity: No data showing genetic mutation from standardized assays
Other Health Effects: Inhalation of mist may cause transient respiratory discomfort
Aquatic Toxicity: Harmful to aquatic organisms at high concentrations; avoid direct discharge to waterways
Persistence and Degradability: Moderately biodegradable through microbial action in soil and water
Bioaccumulation Potential: Expected to have low to moderate bioaccumulation in aquatic species
Mobility in Soil: Mobile in soil, especially where high water content or low organic matter exists
Other Adverse Effects: No evidence of long-term adverse effects at low concentrations in environmental tests
Waste Treatment Methods: Dispose of in accordance with local, regional, and national regulations
Recommended Disposal: Incinerate or treat in chemical waste facility if permitted; avoid landfill when possible
Contaminated Packaging: Rinse container, offer for recycling or dispose with hazardous waste
Precautionary Steps: Ensure complete removal of product from packaging; do not reuse containers for non-hazardous materials
UN Number: Not regulated for road, air, or sea under most conditions
Transport Hazard Class: Not classified as dangerous
Packing Group: Not applicable
Labeling Requirements: None for typical quantities and packaging
Special Transport Precautions: Avoid loading with strong oxidizers or acids; secure tightly during transportation
Environmental Hazards: Not a marine pollutant; prevent large releases en route
OSHA: Not regulated as hazardous under OSHA standards
TSCA: Listed on United States TSCA inventory
EINECS/ELINCS: Registered in European regulatory inventory
Canada (DSL): Listed for use; workplace labeling required
SARA Title III: Not-listed; no reporting required
California Prop 65: No known components listed
Other Applicable Regulations: Compliance required with local, state, and federal laws concerning chemical hygiene practices; consult environmental health for country-specific guidance
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