MSDS: Polypropylene Glycol (9) Butyl Ether

1. Identification

Product Name: Polypropylene Glycol (9) Butyl Ether
Synonyms: PPG-9 Butyl Ether, Polyoxypropylene(9) butyl ether
CAS Number: 9003-13-8
Recommended Use: Solvent, intermediate
Supplier: Manufacturer or distributor contact details required on label
Emergency Phone: Provided by the manufacturer or distributor

2. Hazard Identification

GHS Classification: Eye Irritation, Category 2B; Skin Irritation, Category 3
Signal Word: Warning
Hazard Statements: Causes mild skin irritation, causes eye irritation
Pictogram: Exclamation mark
Precautionary Statements: Wash skin thoroughly after handling, wear eye protection
Hazard Overview: Product can cause discomfort on contact with eyes and skin, inhalation of vapor may irritate respiratory passages

3. Composition / Information on Ingredients

Chemical Identity: Polypropylene Glycol (9) Butyl Ether
Concentration: 100%
CAS Number: 9003-13-8
Impurities: Trace residual monomers from manufacturing may be present

4. First Aid Measures

Inhalation: Move exposed individual to fresh air, keep at rest, seek medical advice if symptoms persist
Skin Contact: Remove contaminated clothing, rinse skin thoroughly with soap and water, consult physician if irritation develops
Eye Contact: Rinse eyes cautiously with water for several minutes, remove contact lenses if present, continue rinsing, get medical advice if discomfort continues
Ingestion: Do not induce vomiting, rinse mouth with water, seek medical help right away

5. Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide
Specific Hazards: Vapors may form flammable mixtures with air, combustion releases carbon oxides
Special Protective Equipment: Firefighters need to wear self-contained breathing apparatus and full protective clothing
Fire-Fighting Instructions: No direct contact with burning material, keep containers cool with water spray to limit risk of rupture

6. Accidental Release Measures

Personal Precautions: Wear suitable protective clothing, gloves, and eye/face protection, ventilate area
Environmental Precautions: Prevent flow into sewers and waterways, contain spill if safe
Spill Clean Up: Absorb with inert material (sand, earth), shovel into containers for disposal, decontaminate area with water and detergent

7. Handling and Storage

Precautions for Safe Handling: Keep container tightly closed, use in well-ventilated area, avoid inhalation and contact with eyes and skin
Storage Conditions: Store in a cool, dry place, away from heat and ignition sources, segregate from strong oxidizers
Specific End Uses: Refer to industrial use guidelines for solvents and processing aids

8. Exposure Controls and Personal Protection

Exposure Limits: No established occupational exposure limit in most jurisdictions
Engineering Controls: Provide adequate local exhaust and general ventilation
Personal Protection: Use chemical-resistant gloves, safety goggles, protective clothing
Respiratory Protection: Use approved respirators if vapor concentrations exceed safe levels
Hygiene Measures: Wash hands after handling, do not eat or drink while using product

9. Physical and Chemical Properties

Physical State: Liquid
Appearance: Clear, colorless to pale yellow viscous liquid
Odor: Mild, ether-like
pH: Not applicable
Boiling Point: 140-260°C (range for this class of compounds)
Melting Point: Below -50°C
Flash Point: Above 100°C
Vapor Pressure: Low at room temperature
Solubility: Miscible with water
Density: 1.01 g/cm³ at 20°C
Viscosity: Moderate to high, depending on ambient temperature

10. Stability and Reactivity

Reactivity: Stable under recommended storage conditions
Chemical Stability: Stable, does not decompose under normal use
Incompatibility: Strong acids, strong oxidizers, alkali metals
Hazardous Decomposition: Carbon monoxide, carbon dioxide upon thermal breakdown
Hazardous Polymerization: Will not occur under normal conditions

11. Toxicological Information

Acute Toxicity: Data for similar polyalkylene glycols show low toxicity
Skin Irritation: Mildly irritating to skin on prolonged contact
Eye Irritation: Causes irritation on contact
Respiratory Sensitization: Not expected to cause sensitization
Carcinogenicity: No data showing carcinogenic effects
Mutagenicity: No mutagenic potential reported
Reproductive Effects: No known effects on reproductive health

12. Ecological Information

Ecotoxicity: Not classified as environmentally hazardous, but releases to water should be avoided
Persistence and Degradability: Expected to be slowly biodegradable
Bioaccumulation Potential: Low potential for bioaccumulation
Mobility in Soil: Likely to have high mobility in aqueous environments due to solubility
Other Adverse Effects: None expected with responsible use and disposal

13. Disposal Considerations

Waste Treatment Methods: Collect and recycle or dispose via licensed chemical waste contractor
Contaminated Containers: Empty containers retain residue, triple rinse and dispose following local regulations
Disposal Guidance: Incineration or chemical treatment recommended in accordance with local, regional, and national environmental requirements

14. Transport Information

UN Number: Not classified as dangerous for transport
Transport Hazard Class: Not regulated
Packing Group: Not applicable
Special Precautions: Secure containers during transit to prevent leakage, avoid extremes of temperature
Marine Pollutant: Not designated as marine pollutant
Shipping Name: Polypropylene Glycol Butyl Ether or as specified on transport documentation

15. Regulatory Information

Safety, Health and Environmental Regulations: Subject to registration, evaluation, and restrictions under REACH in Europe, listed on TSCA inventory in the US
Labeling Requirements: Conform to GHS, OSHA Hazard Communication Standard, and equivalent systems
Workplace Safety: Adhere to national occupational health and safety laws, workers require training in chemical risk control
Substance-Specific Regulations: May be subject to additional state or country-specific rules regarding storage and emissions
Other Regulatory Details: MSDS/SDS must accompany all shipments and workplace uses, updates required with new safety data