Product Name: Polypropylene Glycol (52) Butyl Ether
Synonyms: PPG (52) Butyl Ether, Butyl Polypropylene Glycol Ether
Chemical Family: Polyether Glycol Ether
Recommended Use: Solvent, Intermediate, Chemical Processing
Supplier: Manufacturer or vendor information available on request
CAS Number: 9003-13-8
Emergency Contact: Chemtrec +1-800-424-9300
GHS Classification: Eye irritation - Category 2A, Skin irritation - Category 2, Specific Target Organ Toxicity (Single Exposure) - Category 3
Signal Word: Warning
Hazard Statements: Causes skin and eye irritation. May cause respiratory irritation.
Pictograms: Exclamation mark symbol
Precautionary Statements: Avoid breathing vapors or mists. Wash skin thoroughly after handling. Use only in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.
Other Hazards: May cause central nervous system depression in high concentrations.
Ingredient: Polypropylene Glycol Butyl Ether
Chemical Formula: CxHyOz
Concentration: > 99% (by weight)
Impurities: Trace oligomers, possible low molecular weight byproducts
Additives: None listed for commercial grades
CAS Number: 9003-13-8
Inhalation: Move person to fresh air, keep comfortable for breathing, seek medical attention if symptoms develop or persist.
Skin Contact: Remove contaminated clothing. Rinse skin with water for at least 15 minutes. Seek medical advice if irritation occurs.
Eye Contact: Flush eyes with running water for several minutes. Do not rub eyes. Remove contact lenses if present and easy to do. If irritation persists, consult a physician.
Ingestion: Do not induce vomiting. Rinse mouth with water. Seek medical attention if symptoms develop. Never give anything by mouth if victim is unconscious.
Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide
Unsuitable Extinguishing Media: Direct water jet
Specific Hazards: May give off toxic fumes (carbon monoxide, carbon dioxide) when heated to decomposition, fire may produce dense black smoke
Protective Equipment: Firefighters need self-contained breathing apparatus and protective clothing
Firefighting Instructions: Cool exposed containers with water. Prevent runoff from entering drains or waterways.
Personal Protection: Wear suitable chemical resistant gloves, goggles, and protective clothing to prevent skin and eye contact. Use respiratory protection if ventilation is not adequate.
Environmental Precautions: Prevent material from entering soil, drains, waterways, and sewers.
Methods for Clean-Up: Contain and absorb spillage with inert materials (sand, earth, vermiculite). Collect in suitable containers for disposal. Wash contaminated area with water and detergent. Eliminate all sources of ignition.
Safe Handling: Use in well-ventilated spaces. Avoid breathing vapors/mist. Prevent contact with skin, eyes, and clothing. Ground and bond containers when transferring product.
Storage Conditions: Store tightly closed in original container at room temperature, away from direct sunlight and incompatible materials.
Incompatible Materials: Strong oxidizing agents, strong acids, strong bases
Other Information: Keep away from ignition sources and open flame. Empty containers retain residue and vapor; handle as if full.
Occupational Exposure Limits: No specific workplace exposure limits established for this material
Engineering Controls: Use ventilation (local exhaust) to keep air concentrations below recommended exposure levels.
Personal Protective Equipment (PPE): Chemical safety goggles, protective gloves (nitrile, PVC), protective clothing. Use approved respirator under conditions of insufficient ventilation.
Hygiene Measures: Wash hands, face, and exposed skin thoroughly after handling and before eating, drinking, or using tobacco.
Appearance: Clear, colorless to pale yellow liquid
Odor: Mild, slightly ether-like
Melting Point: Not applicable (liquid at room temperature)
Boiling Point: 220–260°C (varies by grade and molecular weight)
Flash Point: > 110°C (closed cup)
Auto-ignition Temperature: > 250°C
Solubility: Soluble in water
Vapor Pressure: Very low at 20°C
Density: 1.00–1.04 g/cm³
Viscosity: 45–60 cSt at 25°C
pH: Neutral (in aqueous solution)
Chemical Stability: Stable under recommended handling and storage conditions.
Reactivity: May react with strong oxidizers, acids, and bases.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, organic acids.
Conditions to Avoid: Excessive heat, open flame, incompatible materials.
Polymerization: Not expected under normal handling.
Acute Toxicity: Low acute toxicity based on available animal data.
Skin Corrosion/Irritation: May cause mild to moderate irritation with prolonged or repeated contact.
Serious Eye Damage/Irritation: Causes eye irritation.
Respiratory Sensitization: Vapors or mists can irritate respiratory system.
Chronic Effects: No mutagenic, carcinogenic, or reproductive hazards identified in available studies.
Other Effects: High concentrations may cause central nervous system effects such as dizziness or headache.
Ecotoxicity: Not expected to be acutely hazardous to aquatic organisms at typical environmental concentrations.
Persistence and Degradability: Biodegradable under aerobic conditions.
Bioaccumulative Potential: Low potential for bioaccumulation.
Mobility in Soil: Moderate mobility expected in soil.
Other Adverse Effects: Large spills can affect aquatic environments through oxygen depletion or physical fouling.
Waste Treatment Methods: Dispose of through licensed waste disposal contractor. Incineration recommended where permitted.
Container Disposal: Empty containers should be rinsed, punctured, and recycled or disposed in accordance with local, national, and regional regulations.
Special Precautions: Avoid release to environment. Do not discharge to surface water or sewers.
UN Number: Not regulated for transport according to most international regulations
Proper Shipping Name: Polypropylene Glycol Butyl Ether
Transport Hazard Class: Not classified as dangerous goods
Packing Group: Not applicable
Special Precautions: Avoid container damage and handle to prevent spills during transport.
TSCA Status: Listed or exempt
REACH Status: Registered or pre-registered in EU
SARA Title III: Not listed as hazardous under Sections 302, 304, 313
DSL/NDSL (Canada): Listed
Labeling Requirements: Follow local, state, federal, and international requirements
Other Regulations: Comply with local occupational health and safety regulations, chemical inventory requirements, and environmental legislation in relevant regions.
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