Product Name: Polypropylene Glycol #400 Monobutyl Ether
Chemical Family: Polyether Glycol Ethers
Synonyms: PPG Butyl Ether, PPG-400 Monobutyl Ether
Product Code: 400-MBE
Manufacturer: Contact current supplier for details
Emergency Contact: Refer to local emergency contacts and poison control lines
Recommended Use: Industrial solvent, chemical process aid, formulation intermediate
Restrictions on Use: Not intended for food, drug, or cosmetic applications
Classification: Eye irritant, skin irritant, may be harmful if swallowed, inhaled, or absorbed through skin
GHS Label Elements: Exclamation mark symbol; Signal Word: Warning
Hazard Statements: Causes serious eye irritation; may cause skin irritation and respiratory tract irritation; possible harmful effects through prolonged or repeated exposure
Precautionary Statements: Avoid breathing vapors, avoid contact with skin, eyes, and clothing, use only with adequate ventilation, do not eat, drink, or smoke when using this product; wash hands after handling
Other Hazards: Slippery when spilled, can cause central nervous system effects if overexposed
Chemical Identity: Polypropylene glycol monobutyl ether
CAS Number: 9003-13-8 / mixture
Concentration: Greater than 90% by weight
Other Ingredients: Trace stabilizers, water <1%
Impurities: Propylene oxide oligomers, butyl alcohol traces
Inhalation: Move person to fresh air, keep at rest in a position comfortable for breathing, seek medical advice if symptoms develop or persist
Skin Contact: Remove contaminated clothing, rinse skin with plenty of water and soap, seek medical attention if irritation remains
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, continue rinsing, seek immediate medical assistance
Ingestion: Rinse mouth, seek medical attention or call poison center, do not induce vomiting unless directed by medical personnel
Most Important Symptoms and Effects: Eye/skin irritation, dizziness, headache, nausea
Suitable Extinguishing Media: Alcohol-resistant foam, dry chemical, carbon dioxide, water spray
Unsuitable Extinguishing Media: Direct stream of water may spread fire
Hazards from Fire: Vapors may form explosive mixtures with air, combustion yields carbon oxides and unknown toxic fumes
Firefighting Instructions: Evacuate area, use self-contained breathing apparatus, prevent runoff from entering drains
Protective Equipment: Firefighters require full protective clothing, heat and chemical-resistant gear
Personal Precautions: Evacuate unnecessary personnel, ventilate area, avoid skin and eye contact, wear suitable protective equipment
Environmental Precautions: Prevent product from entering drains, soil, and waterways, contain spill with dikes or absorbent material
Methods for Cleanup: Soak up with inert absorbent, collect in suitable container, dispose according to regulations, wash spill site after material pickup
Special Considerations: Clean contaminated surfaces thoroughly, remain alert for slipping hazard, notify authorities if large spills enter environment
Handling: Use personal protective equipment including goggles and gloves, avoid inhaling vapors or contact with skin, practice good industrial hygiene
Storage: Keep container tightly closed in cool, dry, well-ventilated place, away from acids, oxidizers, ignition sources, and direct sunlight
Storage Incompatibilities: Avoid storing near chlorinated solvents, acids, base or reactive substances
Safe Transfer: Ground and bond containers during transfer to prevent static discharge
Other Precautions: Store in original containers, keep away from food and beverages
Exposure Limits: No established limits for PPG 400 monobutyl ether; observe general exposure limits for glycol ethers
Engineering Controls: Use local exhaust ventilation and general dilution ventilation as needed
Personal Protective Equipment: Wear chemical goggles or safety glasses, chemical-resistant gloves such as nitrile, splash-resistant work clothing, suitable respiratory protection if ventilation inadequate
Hygiene Measures: Wash thoroughly after handling, remove contaminated clothing and wash before reuse, keep away from food, drink, and tobacco
Appearance: Clear, colorless or pale yellow liquid
Odor: Mild, ether-like
Odor Threshold: Not available
pH: Typically neutral (6-8)
Melting Point/Freezing Point: Less than -40°C
Boiling Point/Range: Greater than 200°C
Flash Point: 120-140°C (closed cup)
Evaporation Rate: Slower than water
Flammability: Not highly flammable under normal conditions but may form combustible mixtures with air
Vapor Pressure: Less than 1 mmHg at 20°C
Vapor Density: Greater than air
Solubility: Miscible with water and organic solvents
Partition Coefficient (n-octanol/water): Not available
Auto-ignition Temperature: Above 250°C
Decomposition Temperature: Greater than 250°C
Viscosity: 70-100 cP at 25°C
Chemical Stability: Stable under standard temperatures and pressures
Possible Hazardous Reactions: May react with strong oxidizing agents, strong acids, strong bases
Conditions to Avoid: High temperature, open flames, incompatible chemicals, prolonged exposure to air
Incompatible Materials: Oxidizers, acids, bases, some plastics and rubbers
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, low molecular weight hydrocarbons, other toxic vapors
Acute Toxicity: Low toxicity expected for single exposures, higher doses can cause nausea, headache, CNS effects
Skin Corrosion/Irritation: Mild to moderate irritation possible with prolonged or repeated contact
Serious Eye Damage/Irritation: Eye irritation common from direct exposure
Respiratory or Skin Sensitization: Not expected to be a sensitizer, although asthma-like symptoms possible at high concentrations
Chronic Effects: Prolonged inhalation exposure can result in liver and kidney changes, symptoms of overexposure include headache, dizziness, drowsiness
Carcinogenicity: No known carcinogenic properties marked by OSHA, IARC, NTP
Reproductive/Developmental Effects: No conclusive evidence of reproductive toxicity documented
Target Organ Effects: Eyes, skin, respiratory system, central nervous system
Other Information: Seek medical attention if exposed in large quantities
Toxicity to Aquatic Life: Harmful in large amounts, may cause long-term adverse effects in aquatic environments
Persistence and Degradability: Expected to biodegrade over weeks to months, not considered persistent under environmental conditions
Bioaccumulative Potential: Moderate, based on structure and molecular weight
Mobility in Soil: High mobility in soil and water, potential to reach groundwater
Other Adverse Effects: Large spills could impact aquatic organisms, always follow best practices to limit environmental release
Waste Treatment Methods: Dispose in accordance with local, regional, and national regulations
Waste Characterization: Product waste classified as non-hazardous industrial chemical waste, but always verify classification with authorities
Container Disposal: Empty containers retain residue, do not reuse; triple rinse containers, crush and dispose in compliance with local guidelines
Special Instructions: Do not discharge to sewers, surface water, or storm drains; use licensed contractor for large quantity disposal
Regulatory Status: Not listed as hazardous waste, though local laws may apply stricter standards
UN Number: Not regulated as dangerous goods for road, rail, air, or sea
Proper Shipping Name: Polypropylene glycol monobutyl ether
Transport Hazard Class: Not classified
Packing Group: Not applicable
Environmental Hazards: Not a marine pollutant
Special Precautions for Transport: Avoid rough handling, keep drum closures secure, transport upright
Transport Labels: No special labeling required under most jurisdictions
U.S. TSCA Status: Listed
EU REACH Status: Exempt as polymer, monomer registration may apply
OSHA: Not classified as hazardous under OSHA hazard communication standard
Canada DSL: Listed
SARA Title III: Not subject to reporting requirements under SARA 302, 304, 313
California Proposition 65: No components listed
Other Regulatory Listings: Check local, state, and national regulations for information relevant to your site-specific use
Labeling Requirements: Ensure product safety labels are visible, include all appropriate hazard pictograms and warnings in local language
Providing high-quality chemical products and logistics solutions for global trade partners.
