Product Name: O O'-Bis(2-aminopropyl)polypropyleneglycol
Chemical Family: Polyetheramine
SYNONYMS: Polypropylene glycol bis(2-aminopropyl)ether, Jeffamine D
Molecular Formula: CxHyN2Oz
Intended Use: Industrial, specialty chemicals, epoxy curing agent
Manufacturer: Supplier details included on packaging or invoice
Emergency Contact: Refer to Safety Officer or Local Poison Control
GHS Classification: Skin corrosion/irritation: Category 2; Eye damage/irritation: Category 1; Acute toxicity (Oral): Category 4
Hazard Statements: Causes severe skin burns and eye damage, Harmful if swallowed
Signal Word: Danger
Pictograms: Corrosive, Exclamation mark
Precautionary Statements: Wear protective gloves, clothing, and eye protection. Do not breathe mist or vapor. Wash hands thoroughly after handling.
Chemical Name: O O'-Bis(2-aminopropyl)polypropyleneglycol
CAS Number: 9046-10-0
Concentration: 100% (unless diluted for specific use)
Impurities: Trace amounts of allyl chloride, polypropylene glycol
Inhalation: Move person to fresh air. Seek medical attention if respiratory symptoms develop.
Skin Contact: Remove contaminated clothing. Rinse skin with water for at least 15 minutes. Get medical attention if irritation persists.
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses. Continue rinsing. Get immediate medical attention.
Ingestion: Do not induce vomiting. Rinse mouth. Never give anything by mouth to an unconscious person. Call a physician right away.
Most Important Symptoms: Burns, redness, pain, impaired vision, gastric upset.
Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide
Unsuitable Extinguishing Media: Direct water jet (product may float and spread fire)
Hazards: Combustion may produce toxic vapors such as nitrogen oxides, carbon monoxide, carbon dioxide
Protective Equipment: Wear full protective gear including self-contained breathing apparatus
Firefighting Precautions: Stay upwind and remove unaffected containers from fire area if safe. Use water spray to cool exposed containers.
Personal Protection: Use appropriate PPE: gloves, goggles, long sleeves, and face shield
Environmental Precautions: Prevent entry into sewers, soil, and waterways
Spill Clean-up: Absorb with earth, sand, or suitable absorbent material. Collect into chemical waste containers. Use tools designed for chemical management.
Decontamination: Wash spill area with plenty of water and detergent
Handling: Use in well-ventilated areas. Keep away from heat, sparks, and open flames. Avoid skin and eye contact. Prevent aerosol and vapor generation. Keep containers tightly closed.
Storage Conditions: Store in cool, dry, well-ventilated area in original container. Keep away from strong oxidizers. Do not store below freezing. Label containers clearly and keep away from food and beverages.
Exposure Limits: No established OSHA or ACGIH TLV/PEL
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to lower airborne levels
Personal Protection: Chemical-resistant gloves (nitrile, PVC, neoprene), lab coat, apron, and splash goggles or face shield. In case of high vapor concentrations, approved respirator.
Hygiene Measures: Keep hands away from face. Do not eat, drink, or smoke near product. Wash hands and forearms after use.
Appearance: Clear to yellowish liquid
Odor: Ammoniacal, faint
Odor Threshold: No data available
pH (neat): Alkaline (often 10-12)
Melting Point: Below -20°C
Boiling Point: 200–250°C, varies by molecular weight
Flash Point: 185°C (closed cup, typical value)
Evaporation Rate: Slow
Flammability: Not classified as highly flammable
Vapor Pressure: <1 mmHg at 25°C
Solubility: Moderately soluble in water
Partition Coefficient (log Kow): Not determined
Viscosity: 40–200 mPa.s (25°C), depends on molecular weight
Density: 0.99–1.04 g/cm³ at 20°C
Decomposition Temperature: >200°C
Chemical Stability: Stable under standard storage conditions
Reactivity: Reacts with strong oxidizers, acids, isocyanates
Hazardous Reactions: Can release heat and flammable gases on contact with certain chemicals
Conditions to Avoid: Moisture, excessive heat, incompatible materials
Hazardous Decomposition: Nitrogen oxides, carbon oxides, small quantity of ammonia
Acute Effects: Harmful if swallowed; can cause burns to skin and eyes
Inhalation: Possible respiratory irritation
Chronic Health Effects: Prolonged skin contact can cause dermatitis and sensitization
LD50 (Oral, rat): 2,885 mg/kg
LD50 (Dermal, rabbit): 2,980 mg/kg
Carcinogenicity: Not classified as carcinogenic by IARC, NTP, or OSHA
Mutagenicity: No conclusive data
Reproductive Toxicity: Not expected based on available studies
Ecotoxicity: Low acute toxicity to aquatic life. Expected LC50 (fish, 96 hrs): 130 mg/L
Persistence and Degradability: Not readily biodegradable; moderate persistence in environment
Bioaccumulative Potential: Low, given water solubility and molecular structure
Mobility in Soil: Moderate based on physical/chemical properties
Other Adverse Effects: Avoid release to natural water systems to reduce potential risk for aquatic organisms
Waste Handling: Dispose of contents/container in accordance with local/regional/national/international regulations
Methods: Incineration in a licensed facility, chemical landfill for solids and contaminated packaging
Contaminated Packaging: Empty containers must be handled as hazardous waste, must not be reused
Special Precautions: Avoid direct discharge to sewers or surface waters. Consult local environmental authorities.
UN Number: Not regulated under UN recommendations for bulk transportation
Proper Shipping Name: Polyalkylenamine solution (for certain mixtures)
Hazard Class: Not typically classified as a dangerous good
Packing Group: III (if classified as dangerous good, based on pH and quantity)
Environmental Hazards: Not a marine pollutant under IMDG Code
Special Precautions: Avoid accidental release. Secure containers during transit.
Inventory Status: Listed on TSCA (US), EINECS (EU), DSL (Canada), AICS (Australia)
SARA Title III: Not an Extremely Hazardous Substance or Section 313 reportable; subject to reporting if inventory thresholds exceeded
OSHA Hazardous Chemical: Yes, based on acute health effects
REACH Status: Pre-registered or registered in EU
Labeling Requirements: Comply with national and local hazard communication laws, GHS labeling required
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