MSDS for Magnesium D-Gluconate Hydrate

Identification

Product Name: Magnesium D-Gluconate Hydrate
Chemical Formula: C12H22MgO14·xH2O
CAS Number: 3632-91-5
EC Number: 222-848-2
Uses: Dietary supplement, food additive, pharmaceutical ingredient
Supplier: Supplier details appear on order paperwork
Contact for Emergency: Emergency phone numbers for poison control or national chemical hotline

Hazard Identification

GHS Classification: Not classified as hazardous under GHS
Signal Word: None
Hazard Pictograms: None
Hazard Statements: Product does not meet criteria for health or environmental hazard
Precautionary Statements: Use standard work hygiene; avoid unnecessary exposure to dust
Other Hazards: Dust may cause minor respiratory irritation or discomfort

Composition / Information on Ingredients

Chemical Name: Magnesium D-Gluconate Hydrate
Concentration: More than 97%
Synonyms: Magnesium bis-D-gluconate, magnesium gluconate hydrate
Impurities: Trace water, minor organic residues from synthesis
Additives: None indicated

First Aid Measures

Inhalation: Move person to fresh air immediately. Seek medical attention for persistent discomfort.
Skin Contact: Rinse with water. Remove contaminated clothing and wash before reuse.
Eye Contact: Flush eyes thoroughly with water for at least 15 minutes. Consult physician if irritation persists.
Ingestion: Rinse mouth. Drink water to dilute. Call a doctor if large amount was swallowed or effects occur.
Symptoms: Irritation of eyes, mild respiratory symptoms from dust

Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray, foam, dry chemical, or carbon dioxide
Unsuitable Media: None known for this material
Hazards from Fire: Product does not support combustion; thermal decomposition may release carbon oxides and magnesium oxide
Protective Equipment: Wear full protective gear, including self-contained breathing apparatus
Special Precautions: Stay upwind, avoid inhalation of decomposition fumes

Accidental Release Measures

Personal Precautions: Avoid breathing dust. Use personal protective equipment as described below
Environmental Precautions: Prevent large spills from entering drains or surface water
Containment Methods: Sweep up solid product with minimal dust generation. Collect in labeled containers for reuse or disposal.
Cleaning Methods: Clean spill area with water and detergent to remove residues. Ventilate area as needed.

Handling and Storage

Handling: Minimize dust generation. Wash hands before eating, drinking, or smoking. Work in well-ventilated areas.
Storage Requirements: Store in tightly closed containers in a cool, dry, well-ventilated location. Protection from humidity and sources of ignition required.
Special Considerations: Keep away from incompatible substances and moisture. Ensure containers remain tightly sealed when not in use.

Exposure Controls and Personal Protection

Occupational Exposure Limits: No official exposure limits published, treat as nuisance dust (OSHA PEL for particulates not otherwise regulated: 15 mg/m3 total, 5 mg/m3 respirable)
Engineering Controls: Local exhaust ventilation recommended for dusty conditions.
Personal Protective Equipment:
- Respiratory: Approved dust respirator if dust levels are high
- Eyes: Safety glasses or splash goggles
- Skin: Gloves to avoid prolonged contact
- Hygiene: Wash thoroughly after handling

Physical and Chemical Properties

Appearance: White or off-white, odorless, crystalline powder
Odor: Odorless
pH: Aqueous solution typically near neutral
Melting Point: Decomposes above 160 °C
Solubility: Readily soluble in water
Density: About 1.75 g/cm3
Vapor Pressure: Not applicable (non-volatile solid)
Partition Coefficient: Not determined
Boiling Point: Not applicable
Flash Point: Not flammable

Stability and Reactivity

Chemical Stability: Stable under standard storage conditions
Possible Reactions: No dangerous reactions expected with normal materials
Conditions to Avoid: Excess humidity, very high temperature
Incompatible Materials: Strong oxidizers, strong acids
Decomposition Products: Magnesium oxide, carbon dioxide, small amounts of carbon monoxide when heated to decomposition

Toxicological Information

Routes of Exposure: Inhalation, ingestion, skin and eye contact
Acute Toxicity: Low toxicity based on animal models; LD50 (oral, rat) > 5 g/kg
Chronic Toxicity: No known chronic health effects from regular handling
Health Hazards: May cause minor irritation to respiratory tract, eyes, or skin
Sensitization: Not expected to cause allergy or sensitization
Other data: No evidence for carcinogenic, mutagenic, or reproductive hazards

Ecological Information

Ecotoxicity: Product shows low acute aquatic toxicity; not expected to significantly harm aquatic organisms
Persistence and Degradability: Magnesium gluconate hydrates readily degrade in the environment
Bioaccumulation: Not likely to bioaccumulate due to high solubility and natural occurrence of magnesium and gluconate constituents
Mobility in Soil: Mobile in water, may leach into groundwater in significant overuse or spillage
Other Effects: Substantial releases may disrupt local water chemistry by contributing nutrients or altering mineral balance in sensitive aquatic areas

Disposal Considerations

Waste Treatment Methods: Dispose of material as non-hazardous chemical waste in accordance with local, national, or regional regulations
Contaminated Packaging: Rinse empty containers before recycling or disposal
Precautions: Avoid uncontrolled discharge to environment. Use government-approved waste contractors if generating large quantities.

Transport Information

UN Number: Not regulated for transport
Proper Shipping Name: Magnesium D-Gluconate Hydrate
Transport Hazard Class: Not regulated
Packing Group: Not applicable
Special Precautions for Transport: Avoid damage to containers. Keep containers sealed and upright. Prevent moisture ingress during transit.

Regulatory Information

Safety, Health and Environmental Regulations: Not classified as hazardous under major global chemical regulations
Inventory Listings: Listed on US TSCA, EU REACH, Canada DSL, Australia AICS
Labelling Requirements: Not required for hazard labelling on consumer packaging
Other Regulation: Food-grade material must comply with food additive regulations in country of use; pharmaceutical grade to meet pharmacopeia standards
Worker Protection: Employers must provide safety training and ensure access to protective equipment according to workplace safety laws