Material Safety Data Sheet: Magnesium D-Gluconate Dihydrate (Vegan/Vegetarian)

Identification

Product Name: Magnesium D-Gluconate Dihydrate
Synonyms: Magnesium Gluconate, Magnesium (II) D-Gluconate Dihydrate
Product Use: Nutritional and mineral supplement ingredient, food fortification, dietary additive in vegan and vegetarian products
CAS Number: 3632-91-5
Manufacturer: Contacting supplier yields latest name and address
Emergency Telephone: Refer to national poison center or supplier emergency line

Hazard Identification

GHS Classification: Not classified as hazardous by GHS criteria for physical, health, or environmental effects
Label Elements: No GHS symbol required, no signal word
Hazard Statements: Product does not exhibit significant acute health effects in standard use; dust may cause mechanical eye and respiratory irritation
Precautionary Statements: Avoid generating dust; wash hands after handling; use in well-ventilated area
Routes of Entry: Inhalation, ingestion, skin and eye contact

Composition / Information on Ingredients

Main Component: Magnesium D-Gluconate Dihydrate
Percentage: ≥98% by weight
Molecular Formula: C12H22MgO14·2H2O
Molecular Weight: 484.6 g/mol
Impurities: Trace moisture, residual solvents below regulatory thresholds, no known allergenic contaminants
Origin: Sourced from plant or mineral-based starting materials to ensure vegan/vegetarian compliance

First Aid Measures

Inhalation: Move affected person to fresh air immediately; seek medical assistance if cough or discomfort persists
Skin Contact: Rinse area thoroughly with soap and water; remove contaminated clothing
Eye Contact: Flush with plenty of clean water for several minutes; remove contact lenses if present and easy to do; seek further advice if irritation continues
Ingestion: Rinse mouth with water; do not induce vomiting; seek medical guidance for persistent symptoms

Fire-Fighting Measures

Flash Point: Not flammable under normal processing and storage conditions
Extinguishing Media: Use water spray, carbon dioxide, dry chemical or foam; select agents suitable for surrounding materials
Special Hazards: Produces irritating fumes such as carbon oxides when burned at elevated temperatures
Protective Equipment: Firefighters wear self-contained breathing apparatus, gloves, and full protective gear
Explosion Risk: Fine dust dispersed in air has minimal risk of dust explosion under ordinary handling

Accidental Release Measures

Personal Precautions: Use personal protective equipment to avoid inhalation and contact
Environmental Precautions: Prevent spillage from entering drains or watercourses
Methods for Cleanup: Collect material mechanically; use a vacuum equipped with a HEPA filter if available; avoid sweeping to minimize dusting; place in labeled, sealable containers for disposal or recovery
Decontamination: Ventilate spill area, wash residues with plenty of water

Handling and Storage

Safe Handling: Wear suitable gloves, masks, and protective eyewear; use in designated areas with proper ventilation; avoid eating, drinking, or smoking in work space
Storage Conditions: Store in tightly sealed containers made of compatible materials; keep container dry, away from sources of moisture and strong oxidizers; preferred temperature range is ambient, up to 25°C
Incompatibility: Avoid mixing with strong acids, strong bases, oxidizing agents; keep segregated from foods not labeled for supplements

Exposure Controls and Personal Protection

Exposure Limits: No official occupational exposure limit for magnesium gluconate; general dust threshold: 10 mg/m³ (inhalable, total particulates, time-weighted average)
Engineering Controls: Use local exhaust ventilation or process enclosures for dust containment; provide eyewash stations in immediate working area
Personal Protection: Wear dust mask (P2 or N95), safety goggles, latex/nitrile gloves, laboratory coat or coveralls
Hygiene Measures: Wash hands before eating, after handling; launder contaminated clothing before reuse

Physical and Chemical Properties

Appearance: White to off-white, free-flowing, crystalline powder
Odor: Odorless or slight carbohydrate odor
pH (1% solution): 6.5 – 7.5
Melting Point: Decomposes prior to melting, above 170°C
Solubility: Water-soluble, insoluble in non-polar organic solvents
Boiling Point: Not applicable
Density: 1.7 g/cm³
Vapor Pressure: Negligible
Partition Coefficient: Not determined; expected to be low due to high water solubility
Other: Stable under recommended storage; hygroscopic if left open

Stability and Reactivity

Chemical Stability: Stable under normal handling, storage, and temperature range
Reactivity: No hazardous reactions anticipated with common food ingredients; may react with oxidizers or acids at elevated temperatures
Conditions to Avoid: Moisture, excessive heat
Hazardous Decomposition: Produces carbon dioxide, carbon monoxide, magnesium oxides when heated to decomposition
Polymerization: Not known to occur

Toxicological Information

Acute Toxicity: Oral LD50 (rat): greater than 5000 mg/kg, indicating very low toxicity
Irritation: Dust may cause mild and transient mechanical irritation to eyes, skin, and respiratory tract
Chronic Effects: No evidence of carcinogenicity, reproductive toxicity, or mutagenicity found in available literature
Allergy Potential: Not recognized as an allergen or sensitizer
Additional Information: Safe for use in food and supplements at established levels, as recognized by regulatory authorities

Ecological Information

Ecotoxicity: Low immediate risk for aquatic or terrestrial environments; ingredient naturally degrades
Persistence and Degradability: Decomposes to naturally occurring ions and glucose in environment
Bioaccumulation: Unlikely due to water solubility and metabolic breakdown
Mobility in Soil: Highly mobile and disperses readily in water
Other: Not expected to cause adverse effects in natural concentrations used in supplements or food

Disposal Considerations

Product Waste: Dispose according to local, regional, and national legislation; landfilling or incineration in line with non-hazardous organic chemicals
Contaminated Packaging: Clean before recycling whenever possible; if heavily contaminated, treat the same as chemical waste
Recommended Methods: Prevent release to the environment; do not incinerate material with food residues

Transport Information

UN Number: Not regulated as hazardous for transport
Transport Hazard Class: Not applicable
Packaging Requirements: Use sealed, moisture-proof containers; label according to food or supplement regulations
Environmental Hazards: Not considered a marine pollutant; safe for air, road, rail, and sea transport
Special Precautions: Avoid exposure to water and excessive heat during transit

Regulatory Information

Safety, Health, and Environmental Regulations: Listed as a safe, approved ingredient (Generally Recognized As Safe [GRAS] by FDA); compliant with food, supplement, and vegan labeling regulations in main jurisdictions
Labelling: No specific hazard label required, use supplemental food regs for retail products
Inventory Listings: Present in US TSCA, EU REACH, Canada DSL, and other chemical inventories
Workplace Controls: Subject to workplace safety guidelines for chemical handling; standard occupational dust control rules apply