Material Safety Data Sheet: Dipropylene Glycol Monomethyl Ether Mixture of Isomers

Identification

Product Name: Dipropylene Glycol Monomethyl Ether Mixture of Isomers
Synonyms: Propylene glycol methyl ether, DPGME
Recommended Use: Solvent in paints, cleaners, inks, and coatings
Manufacturer: [Enter Company Name and Address]
Emergency Telephone: [Enter Emergency Contact Number]
CAS Number: 34590-94-8

Hazard Identification

Classification: Eye irritation Category 2A, Flammable liquid Category 4
Signal Word: Warning
Hazard Statements: May cause eye irritation. Combustible liquid. Prolonged or repeated exposure can cause skin dryness or cracking. Vapor can cause drowsiness and dizziness.
Precautionary Statements: Wear protective gloves and eye protection. Keep away from heat, sparks, open flames, and hot surfaces. Use only in well-ventilated areas. Wash hands and skin thoroughly after handling.
HMIS Ratings: Health: 1, Flammability: 2, Reactivity: 0

Composition / Information on Ingredients

Chemical Name: Dipropylene Glycol Monomethyl Ether (mixture of isomers)
Chemical Family: Glycol Ether
Chemical Formula: C7H16O3
Concentration: 100%
CAS Number: 34590-94-8
Impurities: Trace levels of propylene oxide derivatives possible

First Aid Measures

Inhalation: Remove person to fresh air. Seek medical attention if symptoms persist.
Skin Contact: Take off contaminated clothing. Wash with soap and water. Get medical advice if irritation develops.
Eye Contact: Rinse with water for at least 15 minutes, lifting eyelids. Remove contact lenses if present. Ask for medical help.
Ingestion: Do not induce vomiting. Rinse mouth with water. Seek immediate medical attention.
Acute and Delayed Symptoms: May cause central nervous system depression, nausea, dizziness, or headache.

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, foam, carbon dioxide, or water mist.
Unsuitable Extinguishing Media: Direct water stream may scatter and spread fire.
Specific Hazards: Vapors can form explosive mixtures with air above 41°C (105°F). Burning produces carbon monoxide and carbon dioxide.
Protective Equipment for Firefighters: Full protective gear and self-contained breathing apparatus. Cool sealed containers with water spray.

Accidental Release Measures

Personal Precautions: Evacuate area if vapor concentration is high. Use protective equipment: gloves, goggles, respirators if needed. Eliminate ignition sources.
Environmental Precautions: Prevent entry into waterways, drains, or sewers. Notify authorities if large amounts escape.
Cleanup Methods: Contain spill with sand, earth, or absorbent materials. Collect residue in tightly sealed containers for disposal. Wash spill area thoroughly.

Handling and Storage

Handling: Avoid breathing mist, vapor, or spray. Avoid contact with skin and eyes. Use in well-ventilated areas. Do not smoke near product.
Storage: Store in cool, dry, well-ventilated area away from sunlight, sparks, and open flames. Keep containers tightly closed and grounded.
Special Instructions: Store away from acids, oxidizers, and strong bases. Use non-sparking tools.

Exposure Controls and Personal Protection

Exposure Limits: ACGIH TLV: 100 ppm TWA; OSHA PEL: 100 ppm
Engineering Controls: Use mechanical (general or local exhaust) ventilation to control airborne vapors.
Personal Protective Equipment: Gloves: Chemical-resistant recommended (nitrile, neoprene).
Eye: Safety goggles or full-face shield.
Respiratory: Approved respirators in poorly ventilated areas.
Other: Protective clothing to prevent skin exposure.
Hygiene Measures: Wash hands and exposed skin before eating, drinking, or smoking.

Physical and Chemical Properties

Appearance: Clear, colorless liquid
Odor: Mild, ether-like
Odor Threshold: 0.05 to 10 ppm
pH: Not applicable
Melting Point: -80°C
Boiling Point: 190 - 192°C
Flash Point: 75°C (closed cup)
Evaporation Rate: 0.04 (butyl acetate=1)
Flammability: Combustible
Vapor Pressure: 0.5 mmHg at 20°C
Vapor Density: 5.1 (air=1)
Specific Gravity: 0.95 (water=1)
Solubility: Completely miscible in water
Partition Coefficient (n-octanol/water): -0.04
Auto-ignition Temperature: 210°C
Decomposition Temperature: Not determined
Viscosity: 3.7 mPa·s at 20°C

Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressure.
Reactivity: Not highly reactive, but can react with strong acids, bases, or oxidizers.
Possibility of Hazardous Reactions: Dangerous polymerization will not occur.
Conditions to Avoid: Excessive heat, sparks, open flames, or sources of ignition.
Incompatible Materials: Strong oxidizing agents, strong acids, and strong bases.
Decomposition Products: Carbon dioxide, carbon monoxide, and other toxic vapors may form when heated to decomposition.

Toxicological Information

Acute Toxicity: Oral LD50 (rat): 5,150 mg/kg; Dermal LD50 (rabbit): 9,500 mg/kg
Inhalation: Excessive inhalation can produce central nervous system effects such as dizziness, headache, and drowsiness.
Skin Contact: Prolonged contact may cause mild irritation and delayed dryness.
Eye Contact: Causes serious eye irritation with redness and pain.
Chronic Effects: Repeated or prolonged exposure could damage the liver or kidneys.
Sensitization: Not considered a sensitizer.
Carcinogenicity: Not classified as a carcinogen by IARC, NTP, OSHA.
Mutagenicity: Not expected to cause genetic defects.

Ecological Information

Ecotoxicity: Fish (LC50, 96 h): > 10,000 mg/L (rainbow trout); Daphnia (EC50, 48 h): > 1,000 mg/L
Persistence and Degradability: Rapidly biodegradable under aerobic conditions.
Bioaccumulative Potential: Low, log Kow -0.04.
Mobility in Soil: High mobility expected due to solubility in water.
Other Adverse Effects: Not expected to cause long-term adverse effects in the environment.

Disposal Considerations

Waste Disposal: Dispose of in compliance with local, regional, and national regulations. Do not dispose into waterways, drains, or soil.
Contaminated Packaging: Empty containers may retain residue; treat as hazardous. Triple rinse and dispose properly.
Recommended Methods: Incineration by licensed contractor or chemical waste landfill.

Transport Information

UN Number: NA1993
Proper Shipping Name: Combustible Liquid, N.O.S. (Dipropylene Glycol Monomethyl Ether)
Transport Hazard Class: Not regulated in drums less than 450 liters (U.S. DOT), regulated as Combustible Liquid otherwise
Packing Group: III
Environmental Hazards: Not classified as marine pollutant
Special Precautions: Keep away from heat, sparks, and flames. Ensure containers remain upright and secure during transport.

Regulatory Information

United States (OSHA): Classified as hazardous due to eye irritant and combustible properties.
United States (TSCA): Listed on the Toxic Substances Control Act Inventory.
SARA Title III (Sections 302/304/311/312): Immediate (acute) and delayed (chronic) health hazards.
California Proposition 65: Not listed.
Canada (DSL/NDSL): Listed on Domestic Substances List.
Europe (REACH/CLP): Registered, complies with the requirements for safety and labeling.
Label Elements (GHS): Signal word: Warning; Hazard pictogram: Exclamation mark.