Material Safety Data Sheet: Di-m-toluoyl-D-tartaric acid

Identification

Product Name: Di-m-toluoyl-D-tartaric acid
Chemical Formula: C18H16O8
Synonyms: Di-(3-methylbenzoyl)-D-tartaric acid
CAS Number: 32634-66-5
Recommended Use: Chiral resolving agent, laboratory chemical, research applications
Manufacturer: Specialized chemical supplier or laboratory
Emergency Contact: Local poison control center or medical facility

Hazard Identification

GHS Classification: Not classified as hazardous by GHS standards
Signal Word: None
Hazard Statements: May cause mild irritation to eyes, skin, or respiratory system with prolonged exposure
Precautionary Statements: Avoid contact with skin and eyes, avoid breathing dust, wash hands thoroughly after handling
Potential Health Effects: Nuisance dust may lead to mild respiratory discomfort, possible sensitization in predisposed individuals, rare allergic reactions on contact

Composition / Information on Ingredients

Chemical Identity: Di-m-toluoyl-D-tartaric acid
Purity: >98% by weight
Impurities: Minor organic byproducts <2% (typical for laboratory-grade material), residual solvents if present, trace inorganic salts
Molecular Weight: 360.32 g/mol

First Aid Measures

General Advice: Take victim to a well-ventilated area, remove contaminated clothing
Eye Contact: Rinse cautiously with water for 15 minutes, lift eyelids occasionally, seek medical attention for persistent irritation
Skin Contact: Wash gently with soap and water, remove contaminated clothing, rinse skin thoroughly, seek medical advice if irritation continues
Inhalation: Move to fresh air, support breathing if needed, seek medical attention if symptoms persist
Ingestion: Rinse mouth, do not induce vomiting unless advised by medical personnel, seek immediate medical attention

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical powder, foam, carbon dioxide
Unsuitable Extinguishing Media: Strong water jet, due to risk of chemical runoff
Specific Hazards: Emits hazardous fumes like carbon oxides on combustion
Special Protective Equipment: Firefighters should wear complete protective clothing including self-contained breathing apparatus
Firefighting Instructions: Remain upwind, prevent chemical runoff from entry into waterways, cool containers exposed to flames with water spray

Accidental Release Measures

Personal Precautions: Use proper personal protective equipment, ventilate area
Environmental Precautions: Prevent spilled material from entering drains or watercourses
Methods for Cleaning Up: Scoop up spilled powder with minimal dust generation, use damp paper towels or absorbent, collect waste in appropriate container for disposal, wash area with water and detergent

Handling and Storage

Handling: Work in well-ventilated areas, avoid creating dust, use gloves and safety goggles, maintain good laboratory hygiene
Storage Conditions: Store in tightly closed containers, keep in a cool, dry, well-ventilated location away from heat sources and incompatible materials
Incompatibilities: Strong oxidizing agents, strong bases, moisture
Storage Class: General chemical storage, non-hazardous organic compounds

Exposure Controls and Personal Protection

Engineering Controls: Chemical fume hood, local exhaust ventilation
Eye Protection: Safety goggles or face shield
Skin Protection: Laboratory coat, appropriate protective gloves (nitrile or latex)
Respiratory Protection: Dust mask or respirator if dust or aerosol formation possible
Workplace Hygiene: Wash hands after handling, avoid eating or drinking near material

Physical and Chemical Properties

Appearance: White to off-white crystalline powder
Odor: Odorless or faint aromatic scent
pH: Slightly acidic in solution
Melting Point: 192–196°C
Boiling Point: Decomposes before boiling
Solubility: Low solubility in water, higher solubility in organic solvents (e.g., ethanol, methanol, acetone)
Vapor Pressure: Not applicable
Partition Coefficient: Not available
Flash Point: Not determined; material is not volatile
Auto-Ignition Temperature: Not available

Stability and Reactivity

Chemical Stability: Stable under recommended conditions of storage and use, sensitive to moisture
Reactivity: No significant reactivity with common materials under ambient conditions
Hazardous Reactions: May react with strong oxidizers or bases, decomposition products include carbon oxides
Conditions to Avoid: Excess moisture, high humidity, elevated temperatures, direct sunlight
Incompatible Materials: Strong acids, oxidizing agents, alkalis
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide, possibly other toxic fumes if combusted

Toxicological Information

Acute Toxicity: Data not fully established, estimated low toxicity on single exposure basis
Routes of Exposure: Skin contact, eye contact, inhalation, ingestion
Skin Corrosion/Irritation: Mild irritant for some individuals, repeated or prolonged exposure may dry skin
Serious Eye Damage/Irritation: May cause temporary discomfort or redness
Respiratory Sensitization: Dust may cause mild respiratory irritation, no known sensitization reported
Carcinogenicity: Not listed as a carcinogen by IARC, NTP, OSHA
Mutagenicity: No data available, no evidence for genotoxic effects
Repeated Dose Toxicity: No significant effects observed in animal studies, if available

Ecological Information

Ecotoxicity: No acute aquatic toxicity expected at typical laboratory concentrations
Persistence and Degradability: Partially biodegradable in soil and water, breaks down to benign substances over time
Bioaccumulation Potential: Low, not expected to build up in aquatic organisms or the food chain
Mobility in Soil: Low to moderate mobility due to partial solubility
Other Adverse Effects: Avoid large releases into the environment, do not flush into water systems

Disposal Considerations

Waste Disposal Method: Collect material and contaminated items for hazardous waste disposal following local, regional, and national regulations
Unused Product Disposal: Dispose as chemical waste in accordance with institutional guidelines
Contaminated Packaging: Rinse containers thoroughly, dispose as chemical waste
Precautions: Do not dump into sewer, water systems, or on ground surfaces

Transport Information

UN Number: Not regulated for transport
UN Proper Shipping Name: Not classified as dangerous goods
Transport Hazard Class: None
Packing Group: None
Environmental Hazards: None
Special Precautions: Keep container tightly closed and protected from physical damage during transit

Regulatory Information

Labelling Requirements: No special labelling required under GHS or OSHA regulations
Regulatory Status: Not subject to major chemical control laws
Workplace Regulations: Observe standard chemical hygiene practices, maintain accessible safety data sheet
SARA Title III Sections 302, 304, 311/312, 313: Not listed
REACH Status: Not registered as a high production volume chemical
State Regulations: No known state-specific regulations apply to this compound