Product Name: Copper Gluconate
Chemical Name: Bis(D-gluconato-O1,O2)copper
CAS Number: 527-09-3
Molecular Formula: C12H22CuO14
Molecular Weight: 453.84 g/mol
Intended Use: Nutritional supplements, food additive, laboratory purposes
Sourcing: Produced without animal-derived substances, suitable for vegan and vegetarian uses
Supplier Details: Name, address, telephone, and emergency contact specific to distribution location
Synonyms: Copper(II) D-gluconate, copper digluconate
Identification Codes: As listed on regulatory databases or packaging
Physical Description: Blue-green powder or crystals, odorless, mild metallic taste
Classification: Classified as hazardous under GHS (Globally Harmonized System); health hazard - toxic to aquatic life; irritant for eyes and skin
Pictograms: Exclamation mark, environmental hazard (see label requirements)
Signal Word: Warning
Hazard Statements: Causes serious eye irritation, skin irritation possible, may damage organs through prolonged or repeated exposure, toxic to aquatic life with long lasting effects
Precautionary Statements: Avoid release to the environment; use protective equipment; wash hands thoroughly after handling
Other Hazards: Not classified as flammable or explosive; avoid creating dust clouds
Symptom Overview: Exposure can lead to nausea, vomiting, abdominal pain, and possible copper toxicity with chronic ingestion
Copper Gluconate: 98-100%
Other Ingredients: No other hazardous contaminants present; composed strictly as copper gluconate for dietary or technical use
Impurities: Heavy metals present in trace amounts below regulatory limits (reportable if known); absence of animal-sourced contaminants
Allergens: None detected, allergen-free production process verified
Eye Contact: Rinse cautiously with water for at least 15 minutes, remove contact lenses if present and easy to do, seek medical attention if irritation persists
Skin Contact: Wash exposed area with soap and water, remove contaminated clothing, consult physician with any persistent irritation
Inhalation: Move person to fresh air immediately, provide artificial respiration if not breathing, seek medical attention for persistent symptoms
Ingestion: Rinse mouth thoroughly, do not induce vomiting, seek immediate medical advice for large ingestion or development of symptoms
Self-protection of First Aiders: Avoid exposure by wearing gloves and eye protection, ventilate area
Most Important Symptoms/Effects (Acute and Delayed): Metallic taste, gastrointestinal discomfort, possible eye or skin irritation, in severe cases copper toxicity (liver/kidney risk)
Suitable Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide to extinguish fire
Unsuitable Extinguishing Media: Avoid using high-pressure water streams directly as they may spread dust
Hazards Combusted Products: Carbon oxides, copper oxides, and irritating fumes may form; use proper respiratory protection
Protective Equipment: Firefighters require self-contained breathing apparatus and full protective gear to prevent inhalation and contact with eyes/skin
Fire/Explosion Hazards: Not classified as flammable, but material may decompose under intense heat releasing hazardous fumes
Special Procedures: Contain contaminated water for proper disposal; cool closed containers exposed to fire with water spray
Personal Precautions: Wear dust mask, protective gloves, eye protection; avoid creating airborne dust; evacuate area for large spills; provide adequate ventilation
Spill Cleanup Methods: Sweep or shovel up material, minimize dust, place in closed containers for proper disposal; use damp cleaning methods for residues
Environmental Precautions: Prevent entry to drains, watercourses, or soil; notify authorities in case of large environmental contamination
Containment: Isolate the spill area, avoid runoff into sewers, block release into natural waters
Decontamination: Thoroughly clean affected surfaces with water after cleanup
Handling Precautions: Wear suitable personal protective equipment; avoid dust generation; keep containers tightly closed; use only in well-ventilated areas; avoid ingestion and contact with eyes/skin
Safe Storage Conditions: Store in cool, dry, well-ventilated location, away from acids and incompatible materials such as strong oxidizers; use original, sealed packaging
Specific Requirements: Protect from direct sunlight and moisture; label all storage containers clearly
Incompatibilities: Strong acids, strong oxidizers which may react violently with copper salts
Hygiene Measures: Wash hands thoroughly after handling, avoid eating, drinking, or smoking in storage areas
Occupational Exposure Limits: Copper (as dust/mists): OSHA PEL 1 mg/m3; ACGIH TLV 1 mg/m3 (copper dust/mist); no established limits for gluconates specifically
Engineering Controls: Use local exhaust ventilation for significant dust production; provide eyewash stations and safety showers nearby
Personal Protective Equipment: Gloves (nitrile or PVC), chemical splash goggles or safety glasses, lab coat, mask or respirator (NIOSH-approved) under dusty conditions
Environmental Controls: Avoid uncontrolled release to the environment, use collection/dust containment systems
Monitoring Recommendations: Regular workplace monitoring for copper dust if in bulk use or industrial application
Appearance: Blue-green crystalline powder
Odor: Odorless
Odor Threshold: Not applicable
pH (10% Solution): 5.5 – 7.5
Melting Point: Decomposes before melting (above 150°C)
Boiling Point: Not applicable (decomposes)
Solubility: Soluble in water, insoluble in alcohol
Partition Coefficient (n-octanol/water): Data not available
Vapor Pressure: Not relevant
Relative Density: Approximately 2.4 g/cm3
Flash Point: Not flammable
Auto-ignition Temperature: Not determined
Evaporation Rate: Not applicable
Viscosity: Not applicable
Decomposition Temperature: Above 150°C
Chemical Stability: Stable under recommended storage and handling conditions
Conditions to Avoid: Excess heat, moisture, direct sunlight, exposure to acids or oxidizers
Incompatible Materials: Strong acids, alkalies, oxidizing agents; material may react producing toxic gases
Hazardous Decomposition Products: Copper oxides, carbon monoxide, carbon dioxide, irritating fumes at high temperature
Polymerization: Does not undergo hazardous polymerization
Reactivity: Does not present significant reactivity hazards during normal use
Acute Toxicity: Oral LD50 (rat): Approximately 300-500 mg/kg (as copper gluconate); ingestion of large quantities may be harmful
Inhalation: Dusts may cause respiratory irritation, coughing, shortness of breath
Skin Contact: Prolonged or repeated contact can cause mild irritation
Eye Contact: May cause serious eye irritation, redness, watering, discomfort
Chronic Effects: Prolonged exposure may cause liver or kidney damage due to copper accumulation
Specific Target Organ Toxicity (Repeated Exposure): Liver, kidneys
Carcinogenicity: Not classified as carcinogenic by IARC, NTP, ACGIH, or OSHA
Mutagenicity, Teratogenicity: No evidence from available data
Medical Conditions Aggravated by Exposure: Wilson’s Disease (inherited disorder of copper metabolism); pre-existing liver or kidney conditions
Ecotoxicity: Highly toxic to aquatic life; copper ions disrupt aquatic organisms, low concentrations can harm fish, invertebrates
Bioaccumulation Potential: Copper can accumulate in aquatic organisms; long-lasting environmental effects possible after release
Mobility in Soil: Copper binds to soils and sediments; mobility low in terrestrial environments but persistent
Persistence and Degradability: Inorganic compound, does not undergo biological degradation
Other Adverse Effects: Avoid discharge into waterways; monitor effluent discharge as per local and international regulations
Waste Treatment Methods: Dispose as hazardous waste in compliance with local, state, national, or international legislation; do not discharge into drains or natural environments
Disposal of Containers/Packaging: Triple rinse empty containers, puncture or crush before proper disposal or recycling
Contaminated Absorbent Material: Dispose in an approved waste facility; labeling and handling according to safety protocols
Special Instructions: For bulk users, neutralize residue before landfill where permissible; consult licensed waste contractor for disposal options
Regulatory References: Follow U.S. EPA, EU, or other agency guidelines for copper-containing waste
UN Number: Not regulated under most transport codes, but verify international/local regulations
Transport Hazard Class: Not classified as dangerous for road/rail/sea/air under ADR, RID, IMDG, IATA
Packing Group: Not assigned
Proper Shipping Name: Copper Gluconate
Environmental Hazards: Material is environmentally hazardous; mark as hazardous to aquatic environment if required by regulations
Special Precautions for User: Prevent shifting of containers during transport, avoid contact with incompatible substances
Bulk Transport Guidance: Use tightly sealed containers, avoid release of dust in loading/unloading zones
Product Status: Food additive (FCC) and pharmacopeia grade (USP), subject to purity standards; allowed for nutritional use under FDA and EFSA guidelines
Inventory Status: Listed in TSCA, DSL, EINECS, AICS, ENCS, KECI as appropriate
Labeling Requirements: Must clearly state hazard warnings, ingredient identification, hazard symbols per GHS or relevant system
SARA Title III (Sections 311/312): Acute health hazard; not subject to Section 313 reporting unless copper content triggers thresholds
California Proposition 65: Not listed as a carcinogen or reproductive toxicant
Additional National/Regional Regulations: Compliant with Veganic/Vegan/Vegetarian labeling where relevant for food/pharma sectors; traceability to non-animal sources maintained
Worker Protection Standards: Covered by OSHA workplace safety regulations on chemical handling
Other Information: Product documentation maintained and available as per REACH and GHS requirements; safety training for handlers recommended
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