Product Name: Chlorhexidine Gluconate
Chemical Formula: C22H30Cl2N10•2C6H12O7
Molecular Weight: 897.8 g/mol
Synonyms: Hibiclens, Peridex, CHG
Recommended Use: Disinfectant, antiseptic in hand washes, wound care, oral rinses
Manufacturer: [Insert supplier name here]
Emergency Contact: Poison Control Center, local emergency number
CAS Number: 18472-51-0
Classification: Skin Irritant (Category 2), Eye Damage (Category 1), Acute Toxicity Oral (Category 4), Hazardous to Aquatic Environment (Acute 1, Chronic 1)
Signal Word: Danger
Hazard Statements: Causes serious eye damage; causes skin irritation; may be harmful if swallowed; very toxic to aquatic life with long-lasting effects
Pictograms: Corrosive, Exclamation Mark, Environment
Precautionary Statements: Avoid contact with eyes, skin, clothing; wear protective gloves/eye protection/face protection; wash hands thoroughly after use; do not let product reach drains or waterways
Routes of Exposure: Inhalation, skin, eyes, ingestion
Ingredient: Chlorhexidine Gluconate
Concentration: Varies, typically 0.5%–4% in solutions
Other Ingredients: Water, surfactants, emulsifiers, preservatives (may include isopropyl alcohol, fragrance, coloring agents)
Impurities: No significant hazardous impurities identified under normal conditions
Inhalation: Move person to fresh air, monitor breathing, seek medical attention if symptoms persist
Skin Contact: Remove contaminated clothing, rinse skin thoroughly with soap and water, seek medical care for ongoing irritation
Eye Contact: Rinse with water for at least 15 minutes, remove contact lenses if present and easy to do, seek immediate medical attention
Ingestion: Rinse mouth with water, do not induce vomiting, get medical support right away if feeling unwell or if a large amount is swallowed
Most Important Symptoms: Redness, irritation, burning sensation of skin and eyes, nausea, stomach discomfort
Suitable Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide
Unsuitable Media: Direct high-pressure water streams can spread the product
Hazardous Combustion Products: Carbon oxides, nitrogen oxides, hydrogen chloride
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective gear
Additional Information: Remain upwind, cool potentially exposed containers with water spray, runoff from fire control may cause pollution
Personal Precautions: Wear gloves, protective clothing, safety glasses; avoid breathing fumes, prevent contact with skin and eyes
Environmental Precautions: Prevent entry into soil, sewers, drains, water sources; inform relevant authorities if large spills occur
Methods for Containment: Contain spill using inert material like sand or earth, do not touch or walk through spilled material
Cleanup Methods: Collect spilled liquid into containers for disposal, wash area with plenty of water after product removal
Handling: Use in a well-ventilated area, keep away from incompatible material, handle following good hygiene and safety practice
Storage: Keep container tightly closed, store in a cool dry place, shield from direct sunlight, keep away from heat and oxidizing agents
Special Precautions: Always replace lid after use, store away from acids, bases, and oxidizers, avoid freezing temperatures
Occupational Exposure Limits: No specific national workplace exposure limit set for chlorhexidine gluconate
Engineering Controls: Use local exhaust or general ventilation to maintain air quality
Personal Protection: Wear nitrile gloves, protective clothing, chemical-resistant safety goggles, and in high concentrations, respiratory protection
Hygiene Measures: Wash hands and face thoroughly after handling, do not eat, drink, or smoke during use
Appearance: Clear to pale yellow liquid
Odor: Mild, medicinal
Odor Threshold: Not established
pH: 5.0–7.0 (for solutions)
Melting Point/Freezing Point: Not applicable (solution); pure: ~132°C
Boiling Point: Not established
Flash Point: Not relevant for dilute solutions
Evaporation Rate: Similar to water
Solubility: Soluble in water
Partition Coefficient (n-octanol/water): Not available
Vapor Pressure: Not determined
Relative Density: 1.06–1.10 (at 20°C)
Viscosity: Slightly viscous
Decomposition Temperature: >230°C (pure)
Chemical Stability: Stable under normal temperatures and conditions, can degrade at high temperatures
Reactivity: Non-reactive with most substances under recommended storage
Incompatible Materials: Strong oxidizing agents, anionic detergents, acids
Hazardous Decomposition: Releases chlorine-containing gases and oxides of carbon and nitrogen under fire conditions
Polymerization: Does not occur
Likely Routes of Exposure: Skin, eyes, ingestion
Acute Toxicity: Oral LD50 (rat): ~1800 mg/kg; Dermal LD50 (rabbit): >2000 mg/kg
Chronic Effects: Repeated skin contact may cause dermatitis, allergy
Carcinogenicity: Not classified as a human carcinogen by IARC, NTP, OSHA
Symptoms: Burning of eyes and mucous membranes, redness, swelling, discomfort, possible allergic reactions
Sensitization: Possible, especially in healthcare workers
Reproductive Toxicity: No reliable data indicating risk
Mutagenicity: Not considered mutagenic in available studies
Ecotoxicity: Highly toxic to aquatic organisms; LC50 (fish, 96h): ~0.05 mg/L
Biodegradability: Not readily biodegradable
Bioaccumulative Potential: Low, does not significantly accumulate in organisms
Mobility in Soil: Mobile, can leach to groundwater if released
Other Adverse Effects: Discharges to water can be damaging even at low concentrations, disrupts aquatic growth and survival
Disposal Methods: Collect and dispose of product as hazardous waste in accordance with local, regional, national regulations
Contaminated Packaging: Rinse containers before disposal, dispose as hazardous waste
Precautions: Prevent leakage into soil, water, and sewage systems, avoid disposal to natural water bodies, follow community waste disposal rules
UN Number: UN 1760 (where applicable, for bulk or concentrated product)
UN Proper Shipping Name: Corrosive Liquid, N.O.S. (Chlorhexidine Gluconate)
Transport Hazard Class: 8 (Corrosive)
Packing Group: III
Marine Pollutant: Yes
Special Precautions: Keep container upright, ensure closure is tight to prevent leaks
Other Transport Notes: Avoid rough handling, protect against physical damage, comply with all local transport regulations
OSHA: Not listed as a hazardous chemical under OSHA Hazard Communication Standard
TSCA: Listed on the United States TSCA Inventory
SARA Title III: Not subject to reporting under Sections 302, 304, 311, 312, 313
California Prop 65: Not listed
EU Classification: Classified as hazardous under Regulation (EC) No 1272/2008
WHMIS (Canada): Classified as D2B - Toxic Material Causing Other Toxic Effects
Other Requirements: Follow local, state, and federal regulations for safety, health, and environmental protection with reference to chemical hygiene practices
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