Product Name: Copper Gluconate Chelate
CAS Number: 527-09-3
Synonyms: Bis(D-gluconato) copper(II), Copper(II) gluconate
Recommended Use: Nutritional supplement, feed additive, laboratory chemical
Supplier: Manufacturer/Distributor contact information provided on request
Emergency Contact: Consult local Poison Control or Emergency Response Numbers
GHS Classification: Acute toxicity (oral, category 4), Eye irritation (category 2A)
Signal Word: Warning
Hazard Statements: Harmful if swallowed, Causes serious eye irritation
Pictograms: Exclamation mark
Precautionary Statements: Wash hands thoroughly after handling, Avoid contact with eyes and skin, Do not eat, drink, or smoke when using product
Other Hazards: Dust may irritate respiratory tract, Prolonged exposure can aggravate copper sensitivity
Chemical Name: Copper Gluconate
Chemical Formula: C12H22CuO14
Concentration: 99% or more
Impurities: Trace metals may be present at low levels
Additives: No intentional additives
Inhalation: Move to fresh air, seek medical attention if symptoms persist
Skin Contact: Remove contaminated clothing, wash affected skin with soap and water
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present, get medical attention if irritation persists
Ingestion: Rinse mouth, do not induce vomiting, seek immediate medical advice
Symptoms: Coughing, shortness of breath, skin redness, eye discomfort, nausea
Notes to Physician: Treat symptomatically, monitor for copper toxicity
Suitable Extinguishing Media: Water spray, foam, dry chemical, carbon dioxide
Unsuitable Media: None known
Hazardous Combustion Products: Copper oxides, carbon oxides
Protective Equipment: Wear self-contained breathing apparatus, protective clothing
Special Precautions: Avoid inhaling fumes, keep away from strong oxidizers during fire response
Personal Precautions: Ventilate area, wear gloves and safety goggles, avoid dust formation
Environmental Precautions: Prevent release into soil and waterways
Method for Clean Up: Sweep or vacuum up spilled material and place in a suitable container, avoid raising dust, wash spill site after handling
Handling: Handle in well-ventilated areas, avoid contact with eyes, skin, and clothing, do not breathe dust, use proper personal protective equipment
Storage: Keep container tightly closed, store in a cool, dry place, avoid exposure to moisture and incompatible substances such as strong acids, bases, and oxidizers, keep away from food and beverages
Exposure Limits: Occupational exposure limit for copper dust and mists (as Cu): 1 mg/m³ (ACGIH TLV)
Engineering Controls: Use local exhaust ventilation, handle in fume hood if possible
Personal Protection: Safety glasses with side shields, chemical-resistant gloves, lab coat or apron, NIOSH-approved respirator if dust levels exceed recommendations
Hygiene Measures: Wash hands before breaks and at end of work, remove contaminated clothing before re-entering public areas
Appearance: Blue-green crystalline powder
Odor: Odorless
Odor Threshold: Not available
pH: 5.0 – 7.0 (1% solution)
Melting Point: 170-175°C (decomposes)
Boiling Point: Not applicable
Flash Point: Not flammable
Evaporation Rate: Not applicable
Flammability: Not classified as flammable
Vapor Pressure: Negligible
Vapor Density: Not applicable
Solubility: Soluble in water
Partition Coefficient (n-octanol/water): Not determined
Auto-ignition Temperature: Not applicable
Decomposition Temperature: Above 170°C
Viscosity: Not applicable
Chemical Stability: Stable under ambient conditions in original packaging
Reactivity: No known hazardous reactions under normal use
Hazardous Reactions: Reacts with strong oxidizers, acids, bases
Decomposition Products: Copper oxides, carbon monoxide, carbon dioxide
Conditions to Avoid: High humidity, open flame, extreme heat
Incompatible Materials: Strong acids, oxidizing agents, strong bases
Routes of Exposure: Inhalation, ingestion, skin and eye contact
Acute Toxicity: Oral LD50 (rat): 232 mg/kg (for copper(II) gluconate)
Skin Corrosion/Irritation: Mild skin irritation possible with prolonged contact
Serious Eye Damage/Irritation: Causes eye irritation
Respiratory Sensitization: Dust can irritate respiratory tract
Germ Cell Mutagenicity: No data available
Carcinogenicity: Not listed as carcinogenic by IARC, NTP, OSHA
Reproductive Toxicity: No data available
Target Organ Effects: Liver, kidneys (after high, repeated doses), GI tract
Symptoms: Abdominal pain, vomiting, diarrhea, headache, dizziness
Ecotoxicity: Toxic to aquatic organisms at high concentrations, copper compounds accumulate in sediment
Persistence and Degradability: Copper ions not biodegradable, gluconate portion degrades in environment
Bioaccumulation Potential: Copper ions can bioaccumulate in aquatic life
Mobility in Soil: Copper binds to soil particles, limited mobility
Other Adverse Effects: High copper levels can disrupt aquatic food chains, excessive soil exposure may harm beneficial microbes
Waste Disposal: Dispose of in accordance with local, state, and federal regulations for chemical waste, avoid release to environment, use approved incineration or landfill methods
Contaminated Packaging: Rinse containers before disposal, dispose of rinsate as hazardous waste
Special Considerations: Do not re-use empty containers, do not flush to surface water or sanitary sewer
UN Number: Not classified as dangerous for transport
UN Proper Shipping Name: Not regulated
Transport Hazard Class: Not applicable
Packing Group: Not applicable
Marine Pollutant: Not applicable at shipment quantities
Transport Precautions: Secure containers for transport, protect from moisture and direct sunlight, keep containers upright, abide by local regulations
Safety, Health and Environmental Regulations: Complies with TSCA inventory, not listed under SARA Title III Sections 302/304/313 for reportable quantities, not classified by DOT/TDG/IATA as hazardous, subject to workplace exposure standards for copper dust/mists in the United States and EU
Label Requirements: List appropriate hazard and precautionary statements per GHS
Inventory Status: Listed on major chemical inventories (TSCA, EINECS, DSL, AICS, ENCS)
REACH Status: Exempted or registered depending on annual volume in the European Union
Other Regulations: Observe all applicable workplace training and hazard communication standards, provide SDS to employees
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