Material Safety Data Sheet: Calcium Gluconate Lactate

Identification

Product Name: Calcium Gluconate Lactate
Chemical Formula: Mixture of Calcium Gluconate and Calcium Lactate
Synonyms: Calcium 2-hydroxypropanoate, Calcium D-gluconate mixture
Recommended Use: Mineral supplement, used in food and pharmaceuticals
Manufacturer: Provided by supplier
Contact Information: Emergency phone and supplier address provided by manufacturer
CAS Number: 299-28-5 (Calcium Gluconate), 814-80-2 (Calcium Lactate)
Relevant Identified Uses: Used in medical, food, and industrial settings where calcium supplementation is necessary

Hazard Identification

Classification: Not considered hazardous under GHS classification for routine handling
Signal Word: None required
Hazard Statements: May cause temporary irritation to eyes, skin, or respiratory tract at high concentrations
Hazard Pictograms: None assigned
Precautionary Statements: Avoid generating dust. Wash hands thoroughly after use. Work in well-ventilated area.
Potential Health Effects: Inhalation of dust can lead to mild respiratory irritation. Eye or skin contact may result in short-term discomfort.
Environmental Hazards: Not classified as environmentally hazardous

Composition / Information on Ingredients

Substances: Blend of Calcium Gluconate and Calcium Lactate
Calcium Gluconate: 60–90% (CAS: 299-28-5)
Calcium Lactate: 10–40% (CAS: 814-80-2)
Impurities: Trace elements from raw materials or processing, typically below regulatory concern
Other Ingredients: No known hazardous additives, fillers, or stabilizers present

First Aid Measures

Inhalation: Relocate to fresh air. Seek medical attention if symptoms persist. Remove source of exposure.
Skin Contact: Remove contaminated clothing. Wash affected area with mild soap and water. Use moisturizing cream if irritation occurs.
Eye Contact: Rinse eyes with clean, running water for at least 15 minutes. Remove contact lenses if applicable. Seek medical help for persistent symptoms.
Ingestion: Rinse mouth with water. Give small quantities of water to drink. Do not induce vomiting. Medical attention usually not required unless large amount happens to be ingested.

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical, foam, or carbon dioxide
Unsuitable Extinguishing Media: None identified
Special Hazards: Product is not flammable. Dust from product may become a minor nuisance in fire but does not fuel flames.
Protective Equipment: Standard firefighting gear including self-contained breathing apparatus
Combustion Products: Possible release of carbon oxides and calcium oxides in intense fire situations
Other Notes: Cool containers with water spray if exposed to heat or flames. Keep personnel away from smoke or fumes.

Accidental Release Measures

Personal Precautions: Wear suitable gloves, safety goggles, and dust mask. Avoid contact with spill material.
Environmental Precautions: Prevent material from entering waterways or drains. Avoid dust generation.
Spill Cleanup Methods: Use non-sparking tools to collect and place in appropriate container. Clean up residual dust with damp cloth or vacuum fitted with HEPA filter.
Disposal: Dispose according to local regulations. Do not flush to sewer.

Handling and Storage

Handling: Open containers carefully. Use dust extraction or local exhaust ventilation to avoid airborne particles. Keep containers tightly closed when not in use. Avoid eating, drinking, or smoking during handling.
Storage: Store in dry, cool, well-ventilated area, away from acids and strong oxidizing agents. Keep out of direct sunlight. Avoid excessive humidity; product can absorb moisture and clump.
Incompatibilities: Strong acids for extended contact, strong oxidizers.
Special Sensitivities: None known for routine storage conditions.

Exposure Controls and Personal Protection

Exposure Limits: No specific occupational exposure limits established for this mixture
Engineering Controls: Recommended use of local exhaust where dust may be generated. General room ventilation is usually sufficient.
Eye Protection: Use chemical splash goggles or safety glasses.
Hand Protection: Use disposable gloves made from nitrile or rubber if prolonged contact expected.
Respiratory Protection: Use dust mask or particulate respirator during processes generating dust.
Skin Protection: Long-sleeved clothing and closed footwear as routine practice.
Hygiene Measures: Wash hands before breaks and after handling. Remove and clean contaminated clothing.

Physical and Chemical Properties

Appearance: White, odorless, crystalline or granular powder
Odor: No significant odor detected
pH (in solution): 5.9–7.5 in water (10% solution)
Melting Point: Decomposes without melting
Boiling Point: Not applicable; decomposes before reaching boiling point
Solubility: Soluble in water, forming a slightly turbid solution
Relative Density: Approx. 1.6 (water = 1)
Vapor Pressure: Negligible at room temperature
Bulk Density: 0.6–0.85 g/cm³, varies with granulation
Partition Coefficient (n-octanol/water): Not applicable
Other Data: Product is stable under normal storage and handling conditions

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions
Reactivity: No specific reactivity hazards identified
Conditions to Avoid: Direct sunlight; contact with strong acids and oxidizers
Incompatible Materials: Strong acids can cause decomposition, releasing gases. Avoid mixing with strong oxidizers.
Hazardous Decomposition Products: Thermal decomposition can produce carbon oxides and calcium oxide
Polymerization: Will not occur under expected conditions of use

Toxicological Information

Acute Toxicity: Low acute oral toxicity reported; LD50 (oral, rat) generally greater than 2000 mg/kg
Skin Corrosion/Irritation: Not expected to cause lasting skin irritation
Eye Damage/Irritation: Dust may cause mechanical irritation
Respiratory or Skin Sensitization: No sensitizing effects observed during normal use
Carcinogenicity: Not listed as carcinogen by IARC, NTP, or OSHA
Reproductive Toxicity: No reproductive hazards recognized
Other Health Effects: Large ingestion amounts may cause mild gastrointestinal upset; excessive inhalation can trigger cough or throat discomfort

Ecological Information

Ecotoxicity: Not considered harmful to aquatic or terrestrial environments at typical discharge levels
Persistence and Degradability: Components are biodegradable; product will gradually break down in the environment
Bioaccumulative Potential: Not expected to bioaccumulate in organisms
Mobility in Soil: Product is water soluble, may leach in soil but will dissociate rapidly to form calcium and organic acid salts
Other Adverse Effects: Rapid neutralization or dissociation in nature, low risk of long-term ecological effect

Disposal Considerations

Waste Treatment Methods: Collect and place discarded product in containers for landfill or incineration as per local regulations
Unused Product: Can be disposed of as non-hazardous industrial waste in compliance with environmental standards
Contaminated Packaging: Clean containers and recycle or dispose as local requirements dictate
Sewage Disposal: Avoid discharge to municipal sewers or natural waterways without prior treatment; notify authorities in the event of significant release

Transport Information

UN Number: Not regulated for transport
Proper Shipping Name: Not classified as dangerous goods by DOT, IATA, or IMDG
Transport Hazard Class: Not assigned
Packing Group: Not assigned
Marine Pollutant: Not a marine pollutant
Special Precautions: Protect from excessive moisture and mechanical damage during shipping

Regulatory Information

TSCA Inventory: Ingredients listed or exempt
REACH Status: All components meet registration requirements
OSHA Status: Not subject to specific workplace safety rules in the United States
WHMIS Classification (Canada): Not controlled
SARA Title III: Not listed as hazardous
Other National Inventories: Product components appear on global chemical inventories where required for marketing
Labeling Requirements: Standard precautionary labeling for nuisance dust recommended