Material Safety Data Sheet: Calcium D-Gluconate

Identification

Product Name: Calcium D-Gluconate
Other Names: Gluconic acid, calcium salt
Chemical Formula: C12H22CaO14
CAS Number: 299-28-5
Recommended Use: Used in medicine, food additives, and supplements for calcium deficiency
Supplier: Please refer to packaging details
Emergency Contact: Refer to local emergency contact services

Hazard Identification

Hazard Classification: Not classified as hazardous under OSHA Hazard Communication Standard
Label Elements: No signal word, no pictogram required
Hazards to Human Health: Low risk from normal exposure; dust may cause mild eye or respiratory irritation
Environmental Hazards: Low expected environmental impact with regular usage
Other Hazards: Not combustible; dust buildup in work areas may make floor slippery

Composition / Information on Ingredients

Chemical Substance: Calcium D-Gluconate
Ingredients: About 98-100% calcium gluconate by weight
Impurities or Additives: May contain trace levels of related salts or moisture, not considered hazardous by GHS standards

First Aid Measures

Eye Contact: Rinse gently with water for at least 10 minutes; seek medical help if irritation continues
Skin Contact: Remove with water and mild soap
Inhalation: Move to fresh air; seek medical advice if symptoms like coughing or sneezing don’t improve
Ingestion: Rinse mouth; give water to drink; medical attention usually unnecessary if small amounts swallowed
Advice for Medical Responders: Treat based on symptoms; no specific antidote required

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide
Special Hazards: Decomposes above 150°C releasing CO and CO2; dense dust may suppress oxygen close to fire
Protective Equipment: Wear self-contained breathing apparatus and protective clothing
Precautions: Avoid breathing dust, stay upwind, keep containers cool with water spray

Accidental Release Measures

Personal Precautions: Avoid contact with eyes and skin; wear dust mask and gloves
Environmental Precautions: Prevent large spills from entering drains or surface water
Cleanup Methods: Sweep up and place in suitable containers for proper disposal; ventilate area
Containment: Use damp cloths to minimize dust formation; avoid dry sweeping if dust level high

Handling and Storage

Handling: Avoid creating dust clouds; keep area clean and use proper ventilation; wear protective equipment for eyes and respiratory system
Storage Conditions: Store in cool, dry areas; keep container tightly closed and away from direct sunlight
Incompatible Materials: Avoid strong acids and oxidizing agents
Safe Storage Advice: Use shelves to prevent damage and keep chemical off floor in original containers

Exposure Controls and Personal Protection

Limit Values: No specific workplace exposure limits determined
Engineering Controls: Use local ventilation or extraction systems in confined spaces
Personal Protection: Safety goggles, dust mask, chemical-resistant gloves, lab coat
Hygiene Measures: Wash hands thoroughly after handling; no eating or drinking near work area

Physical and Chemical Properties

Appearance: White to off-white crystalline powder
Odor: Odorless
pH: Neutral, typically around 6.5–7.5 (5% solution)
Melting Point: Above 150°C decomposition
Solubility: Soluble in water
Density: About 1.7 g/cm³
Boiling Point: Not applicable
Other Properties: Stable under normal temperatures and pressures

Stability and Reactivity

Reactive Properties: Stable under recommended storage and handling conditions
Conditions to Avoid: High temperatures, direct sunlight, strong acids and oxidizers
Decomposition: Decomposes at high temperatures forming carbon oxides
Polymerization: Not known to undergo hazardous polymerization

Toxicological Information

Routes of Exposure: Inhalation, skin contact, ingestion, eye contact
Short-term Effects: Dust may cause minor irritation to eyes, skin, or respiratory system
Long-term Exposure: Not expected to cause adverse health problems
Acute Toxicity: Oral LD50 (mouse): >5000 mg/kg
Sensitization, Carcinogenicity, Mutagenicity: No known data indicating any sensitization or cancer risks

Ecological Information

Aquatic Toxicity: Low risk with moderate use; low solubility limits potential impact
Persistence and Degradability: Breaks down naturally in soil and water; not persistent
Bioaccumulation: Not expected to bioaccumulate
Mobility in Soil: High mobility in water; limited impact in terrestrial settings

Disposal Considerations

Disposal Methods: Recycle or dispose of in accordance with local, regional, and national regulations
Packaging Disposal: Clean, empty packaging can be recycled or disposed as non-hazardous waste
Special Requirements: Avoid disposing of large amounts into sewer or open water

Transport Information

UN Number: Not regulated for transport
Transport Hazard Class: Not considered hazardous
Packing Group: None
Environmental Hazards for Transport: Not dangerous for environment during shipment
Other Information: Secure tightly closed containers during transportation to prevent leaks or spills

Regulatory Information

OSHA: Not classified as hazardous
TSCA Status: Listed
GHS Classification: Not classified
Other Regulations: Complies with REACH, EINECS requirements
Right to Know: Ingredients and safety information made available to all employees in workplaces using calcium D-gluconate