Material Safety Data Sheet (MSDS) for Butoxypolypropylene Glycol 400

1. Identification

Product Name: Butoxypolypropylene Glycol 400
Chemical Family: Polyether Polyol
Chemical Formula: Varies, typically C12H26O5
Synonyms: Polyoxypropylene Butyl Ether, Butyl Polypropylene Glycol Ether
Recommended Use: Intermediate in chemical processes, surfactant formulations, lubricant, antifoaming agent
Manufacturer: Supplier contact details available upon request
Emergency Phone Number: Company-designated emergency response line

2. Hazard Identification

Classification: Not classified as a hazardous substance under standard OSHA criteria
Label Elements: Non-flammable, not toxic under normal use, slight risk from prolonged skin or eye contact
Hazard Statements: May cause mild irritation to eyes or skin on repeated contact
Precautionary Statements: Avoid prolonged exposure, use personal protective equipment, wash skin after handling
Routes of Exposure: Inhalation, skin contact, ingestion
Target Organs: Respiratory system, eyes, skin

3. Composition / Information on Ingredients

Chemical Name: Butoxypolypropylene Glycol 400
CAS Number: 9003-13-8
Quantity: > 98% by weight
Impurities: Trace residual catalyst, water (< 2%)
Other Ingredients: None of significance in typical batches

4. First Aid Measures

Eye Contact: Flush eyes gently with water for 15 minutes, remove contact lenses if present, seek medical care if irritation persists
Skin Contact: Wash exposed skin thoroughly with soap and water, remove contaminated clothing and launder before reuse
Inhalation: Move the person to fresh air, keep comfortable for breathing; if cough or discomfort continues, get medical attention
Ingestion: Do not induce vomiting, rinse mouth with water, seek medical assistance if symptoms present
Most Important Symptoms: Mild irritation of eyes, skin dryness or redness
Note to Physician: Treat symptomatically, product unlikely to cause severe systemic effects

5. Fire-Fighting Measures

Suitable Extinguishing Media: Water fog, dry chemical, foam, carbon dioxide
Unsuitable Media: Direct water jet can cause splattering
Flash Point: Over 150°C (closed cup)
Fire Hazards: May emit carbon monoxide, carbon dioxide, and irritating vapors in fire
Protective Equipment: Self-contained breathing apparatus, protective clothing for firefighters
Special Procedures: Cool containers with water spray, control runoff to prevent environmental contamination

6. Accidental Release Measures

Personal Precautions: Wear suitable gloves, goggles, and boots to avoid skin and eye contact
Environmental Precautions: Prevent runoff into drains, surface or ground waters
Spill Clean-Up: Absorb on inert material (sand, diatomaceous earth), collect for disposal in sealed containers
Decontamination: Wash affected area with plenty of water after initial cleanup
Secondary Hazards: Slippery surfaces may pose fall risk after spill

7. Handling and Storage

Handling: Use in well-ventilated area, avoid repeated or prolonged contact with skin, do not eat or drink while handling chemicals
Storage Conditions: Keep in tightly closed original container, store in cool, dry, and well-ventilated place, protect from freezing and direct sunlight
Incompatible Materials: Strong oxidizers, acids, bases
Safe Transfer: Ground all transfer equipment to prevent static discharge, avoid spills and splashes
Special Packaging: Use approved chemical-resistant containers only

8. Exposure Controls and Personal Protection

Engineering Controls: Local exhaust ventilation or general ventilation in work area
Exposure Limits: No established occupational exposure limits for Butoxypolypropylene Glycol 400
Personal Protective Equipment: Safety goggles, chemical-resistant gloves (nitrile or neoprene), long-sleeved coveralls
Respiratory Protection: Not required under normal conditions, use mask if vaporization occurs
Hygiene Measures: Wash hands and face before eating, drinking, or smoking, remove contaminated clothing and wash thoroughly

9. Physical and Chemical Properties

Appearance: Clear, colorless to pale yellow liquid
Odor: Mild, slightly ether-like
pH: Neutral (in solution)
Melting Point/Freezing Point: Less than -50°C
Boiling Point: Approximately 200-250°C
Flash Point: >150°C
Evaporation Rate: Low
Vapor Pressure: Negligible at 20°C
Solubility: Soluble in water, organic solvents
Density: About 1.0-1.05 g/cm³ at 25°C
Viscosity: Low to moderate
Partition Coefficient (n-octanol/water): Data not available
Auto-ignition Temperature: Data not available

10. Stability and Reactivity

Chemical Stability: Stable under recommended storage and handling conditions
Reactivity: Inert to most substances under normal conditions
Hazardous Polymerization: Will not occur
Incompatible Materials: Strong oxidizers, acids, strong bases, reactive metals
Decomposition Products: Carbon monoxide, carbon dioxide, low molecular weight hydrocarbons at high temperatures
Conditions to Avoid: Excessive heat, flame, open spark sources, direct sunlight

11. Toxicological Information

Acute Toxicity: Low toxicity, oral LD50 in rats > 5000 mg/kg
Skin Corrosion/Irritation: Minimal irritation on contact, prolonged or repeated exposure may cause dryness
Eye Damage/Irritation: Can cause mild, reversible irritation
Respiratory Sensitization: No reports of sensitization
Carcinogenicity: Not listed as carcinogen by IARC, NTP, OSHA
Mutagenicity: Not mutagenic based on available data
Reproductive Toxicity: No data indicating reproductive effects
Chronic Effects: No evidence of chronic health effects at usual exposure levels

12. Ecological Information

Ecotoxicity: Low toxicity to fish and aquatic invertebrates, EC50 values typically > 100 mg/L
Degradability: Expected to be biodegradable, breaks down in environment over time
Bioaccumulation Potential: Low, does not accumulate significantly in aquatic organisms
Mobility in Soil: Moderate to high mobility, soluble in water
Persistence: Moderate persistence under some conditions, eventual biodegradation expected
Other Adverse Effects: No known significant effects on environment at responsible use levels

13. Disposal Considerations

Waste Disposal: Dispose of in accordance with local, state, and federal regulations
Container Disposal: Empty containers may retain residues, triple rinse and offer for recycling or disposal through authorized waste handler
Methods of Disposal: Incinerate within permitted facility, avoid landfill where possible
Do Not: Discharge into waterways, sewer systems, or uncontrolled environments

14. Transport Information

UN Number: Not regulated
DOT (U.S.A.): Not classified as hazardous for transport
ADR/RID (EU): Not regulated for land transport
IMDG (Sea): Not regulated
IATA (Air): Not regulated for air shipment
Special Precautions: Secure containers to prevent shifting or leakage during transit

15. Regulatory Information

OSHA Hazard Classification: Not hazardous
TSCA Status: Listed in Toxic Substances Control Act Inventory
REACH Status: All components registered or pre-registered under European REACH regulation
SARA Title III: Not subject to reporting under Sections 302, 304, 313
WHMIS (Canada): Not controlled
Inventory Listings: Present on AICS (Australia), DSL (Canada), ENCS (Japan), EINECS/ELINCS (Europe)
Label Requirements: Standard workplace hazard communication labels recommended, though not mandatory for this substance