MSDS: (2S,3S)-D-(-)-Tartaric Acid

Identification

Product Name: (2S,3S)-D-(-)-Tartaric Acid
Chemical Synonyms: D-(-)-Tartaric Acid; L-(+)-Tartaric Acid (enantiomer); D-Tartaric Acid
Chemical Formula: C4H6O6
CAS Number: 147-71-7
Molecular Weight: 150.09 g/mol
Recommended Use: Acidulant in food, chiral chemical synthesis, analytical chemistry
Manufacturer Contact: Provided on commercial MSDS
Emergency Phone: Provided on commercial MSDS

Hazard Identification

GHS Classification: Eye irritation, Category 2A; Skin irritation, Category 2
Signal Word: Warning
Hazard Statements: Causes serious eye irritation; Causes skin irritation
Pictograms: Exclamation mark
Precautionary Statements: Avoid breathing dust; Wash hands thoroughly after handling; Wear protective gloves and eye protection; If in eyes, rinse continuously with water; Seek medical advice if irritation persists

Composition / Information on Ingredients

Chemical Name: (2S,3S)-tartaric acid
Synonym: D-(-)-tartaric acid
Concentration: ≥99%
Other Components: No relevant impurities or additives influencing classification
CAS Number: 147-71-7

First Aid Measures

Inhalation: Move person to fresh air, keep comfortable for breathing, seek medical attention if symptoms continue
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, continue rinsing, get medical attention if irritation persists
Skin Contact: Remove contaminated clothing, wash with soap and water, seek advice if irritation develops
Ingestion: Rinse mouth, drink water to dilute, avoid inducing vomiting, obtain medical advice if feeling unwell or symptoms develop
Most Important Symptoms: Eye redness, tearing, mild skin rash, gastrointestinal discomfort if ingested in quantity

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical powder, carbon dioxide, foam
Hazardous Combustion Products: Carbon oxides (CO, CO2), acrid fumes
Special Protective Equipment: Standard firefighting protective gear, self-contained breathing apparatus
Specific Hazards: Product is not flammable but may cause irritation to mucosal linings if decomposed
Advice for Firefighters: Move containers if safe, avoid breathing fumes, use water to cool fire-exposed surfaces
Flash Point: Not determined (Organic acid, high melting point)

Accidental Release Measures

Personal Precautions: Use personal protective equipment, ensure adequate ventilation, avoid creating dust clouds, do not touch or walk through spilled material without protection
Environmental Precautions: Prevent product from entering drains or waterways, sweep up to prevent release, inform responsible authorities if large spills reach the environment
Clean-Up Methods: Sweep or vacuum up spilled material, avoid generating dust, place in suitable labeled container for recovery or disposal, wash affected area with water

Handling and Storage

Handling: Wear gloves, goggles, and protective clothing, avoid contact with eyes, skin, and clothing, ensure areas are well ventilated, avoid inhaling dust, do not eat or drink near handling area
Storage: Store in a cool, dry, well-ventilated place, keep in tightly closed container, keep away from incompatible substances such as bases and oxidizing agents, protect from moisture, store away from food and drink

Exposure Controls and Personal Protection

Exposure Limits: No specific occupational exposure limits established
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended guidelines
Personal Protective Equipment: Safety glasses with side-shields, gloves made from impervious material (e.g., nitrile), laboratory coat or coveralls, dust mask or respirator in case of dust formation
Hygiene Measures: Wash hands after handling, change contaminated clothing, do not eat or drink in work area

Physical and Chemical Properties

Appearance: White, crystalline solid
Odor: Odorless
pH: Approximately 2.2 (1% solution in water)
Melting Point: 170°C–175°C (decomposes above this temperature)
Boiling Point: Decomposes before boiling
Solubility: Soluble in water (139 g/L at 20°C), slightly soluble in ethanol
Density: 1.79 g/cm³
Flash Point: Not applicable
Partition Coefficient (log Pow): -2.65
Vapor Pressure: Negligible at ambient temperature

Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures, hygroscopic
Hazardous Reactions: Reacts with strong oxidizers, strong bases, forms carbon oxides upon decomposition
Conditions to Avoid: Moisture, high temperatures, open flames
Incompatible Materials: Strong bases, strong oxidizing agents
Decomposition Products: Carbon monoxide, carbon dioxide, organic acids

Toxicological Information

Acute Toxicity: Oral LD50 (rat): 4800 mg/kg
Skin Irritation: Slight irritation possible with prolonged contact
Eye Irritation: Causes severe eye irritation
Respiratory Sensitization: May cause irritation to respiratory tract if dust inhaled
Chronic Effects: No evidence of carcinogenicity, mutagenicity, or reproductive toxicity
Symptoms of Exposure: Red eyes, dry or cracked skin, irritation of mucous membranes, stomach discomfort if ingested in significant amounts

Ecological Information

Ecotoxicity: Low acute aquatic toxicity, rapid biodegradation in soil and water
Mobility: High solubility in water, unlikely to bioaccumulate
Persistence and Degradability: Readily biodegradable by microorganisms under aerobic and anaerobic conditions
Bioaccumulative Potential: Not expected due to low log Pow
Other Adverse Effects: At high concentrations, may lower the pH of water, affecting aquatic life

Disposal Considerations

Disposal Methods: Dispose of as non-hazardous organic waste according to federal, state, and local regulations
Container Disposal: Triple rinse and dispose of according to regulatory requirements
Avoid Release: Prevent dumping into drains, watercourses, or unapproved landfill
Recycling: If possible, recover and reuse in process where allowable

Transport Information

UN Number: Not classified as hazardous for transportation
Proper Shipping Name: Tartaric Acid
Transport Hazard Class: Non-regulated
Packing Group: Not applicable
Environmental Hazards: None identified for transportation, ensure container integrity
Special Precautions: Protect containers from physical damage and moisture

Regulatory Information

TSCA Status: Listed
REACH Registration: Registered and compliant
OSHA Hazards: Eye and skin irritant
SARA Title III: Not listed as a hazardous substance
WHMIS Classification: D2B (Toxic Material Causing Other Toxic Effects)
California Proposition 65: Not listed
Additional Notes: Subject to workplace labeling and hazard communication standards
Other Regulatory References: Compliant with Food Chemical Codex for food use, meets EFSA/JECFA specifications