2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole: A Detailed Look

Historical Development

Chemists first synthesized 2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole in the late twentieth century, right at the surge of polymer and plastics research. Demand for better UV protection in plastics and coatings drove much of that work, pushing companies and labs worldwide to look for molecules that could shield products from sun damage without leaching out or causing harm to people. The chemical structure grew out of earlier benzotriazole UV stabilizers, but modifications gave it stronger photo-stability, longevity, and a broader application range. Over time, production scaled up as global manufacturers saw its value for automotive interiors, exterior paints, and transparent films. By the 1990s, formulations were entering mainstream plastics and coatings, responding to stricter standards about color retention, safety, and product life.

Product Overview

This compound has filled a genuine need for tough, light-resistant additives in polymers like polypropylene, polycarbonate, polyvinyl chloride, and acrylics. Compared to other UV absorbers, it holds onto both strength and transparency, side-stepping the yellowing or brittleness that develops when polymers face months or years of sunlight. Its broad absorption spectrum, targeting both UV-A and UV-B, stretches its protective qualities. Manufacturers can add it to masterbatches, coatings, films, fibers, and adhesives. Its robust protection means garden equipment, outdoor textiles, and auto dashboards all last longer in outdoor or high-light environments.

Physical & Chemical Properties

2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole presents as a pale-yellow crystalline powder, most often handled in its pure or microcrystalline form. It stands out for a melting point around 156-162°C, which gives it flexibility for thermoplastic processing. Poor water solubility keeps it locked in place within polymer matrices. The compound dissolves well in organic solvents like acetone, toluene, and chlorinated hydrocarbons. Its molecular structure, with both tert-butyl groups and a chloro substituent, gives high resistance against oxidation, heat, and fading. For me, seeing firsthand how stable such molecules remain after repeated accelerated weathering impresses—less leaching, less breakdown, better performance over years.

Technical Specifications & Labeling

The market demands detailed tech sheets for this chemical. Typical purity measures above 98%. Moisture, heavy metals, and volatile fractions get capped at much lower values. Granular or microprill formats make it easier to dose and disperse in masterbatch production, especially for thin films or fibers. Labels show the batch number, production date, and all necessary hazard pictograms. Safety Data Sheets list handling and storage rules, identifying UN number and transport category. Some regions demand clear labeling for RoHS, REACH, and other environmental compliance metrics—manufacturers make sure these get checked by third parties and internal labs. Every batch that leaves a reputable plant stacks up against international norms such as ISO 9001.

Preparation Method

Synthesis usually follows a multi-step path, starting with alkylation of phenol with tert-butyl groups, followed by diazotization and coupling with an aniline derivative, and finally cyclization to yield the benzotriazole ring. Chlorination at the aromatic ring needs stringent control to achieve the 5-position selectively, as any over-chlorination affects performance. Modern routes rely on refined catalysts, solvent recovery, and closed-loop reactors; waste minimization and recycling have improved with every decade. In the lab, monitoring reaction progress by thin-layer chromatography or HPLC ensures tight specs. Industrial practice uses large stainless-steel vessels with agitation and inert gas blanketing, reducing exposure risks and maintaining consistent properties batch after batch.

Chemical Reactions & Modifications

This triazole can serve as a platform for chemical modification, though most customers use it straight. Addition or substitution on the phenol or triazole ring tailors UV absorption profiles, boosting efficiency in special applications. Its main reactivity lies at the hydroxyl group, where some surface coaters graft the molecule onto larger polymers. In oxidative conditions, the molecule shows remarkable resilience, a feature that matters if someone’s building outdoor composites or car headlamps. My experience working with plastics machinery shows how additives with less stability can produce byproducts or break down plastic chains; this benzotriazole stands strong, resisting many common degradation pathways.

Synonyms & Product Names

Across catalogs and chemical registries, this substance pops up under several names: Tinuvin 327, UV-327, Chimassorb 327, and the systematic moniker listed in CAS and various pharmacopeias. Distributors and OEMs might skip long chemical descriptors entirely in documents, highlighting only these brand or trade names. Identical structures, no matter the supplier, must tally with global CAS reference number 3864-99-1.

Safety & Operational Standards

Safety standards for handling focus on minimizing dust inhalation and direct skin exposure, as respirable dust could irritate airways. Good industrial hygiene suggests gloves, goggles, and dust masks in areas where the powder could become airborne. Although not classified as carcinogenic or acutely toxic, the compound should be kept away from food and water sources during storage. Regulatory bodies have tested and classified its hazards, with guidance for fire-fighting (dry chemical, foam, or CO2 recommended), spill cleanup (sweep or vacuum with anti-static equipment), and packaging (fiber drums with liners, sealed buckets). Regular ventilation checks and spill containment keep workers safe—something every quality plant manager enforces without debate.

Application Area

The reach of this compound cuts across construction, automotive, packaging, and agricultural films. Weathering tests on plastics used in windows, greenhouse covers, and pool linings show how much longer treated products resist yellowing and cracking under harsh sunlight. It goes into adhesives for laminates and specialty coatings for glass, too. Paints benefit from higher color retention, avoiding the ‘chalking’ that happens outdoors on cars, bikes, or building panels. My time touring an auto parts plant hammered home how interior dashboards, loaded with this additive, handle years of sun without warping or losing gloss—a clear win for durability and value.

Research & Development

The chemical draws ongoing interest from R&D teams keen on better performance and greener chemistry. Labs examine structure-property relationships by tweaking substituent groups, searching for lower migration and better heat stability. Efforts look at blending it with other stabilizers, antioxidants, or HALS (hindered amine light stabilizers) to build synergistic packages for tough markets like solar panels and optics. Academic partnerships have mapped out photodegradation pathways with high-power testing, using mass spectrometry and infrared analysis to watch how the molecule defends polymers under simulated sunlight. In-house corporate teams study how to drop additive levels further, trusting this stabilizer’s power to stretch resources and hit lower VOC targets.

Toxicity Research

Multiple agencies and independent labs have run acute and chronic toxicity trials—oral ingestion, dermal exposure, and inhalation routes all get checked. Results consistently place the chemical in a low-hazard category, with minimal acute effects and no convincing carcinogenic or mutagenic outcomes under standard conditions. Chronic testing, often with rodents over lengthy exposures, has yet to highlight concerns that would warrant wide-ranging regulatory action. Environmental studies consider its low water solubility and high binding to soils and plastics, reducing real-world release risk. I’ve watched company chemists assess wastewater and run bioassays, checking against the newer, lower limits set by evolving rules.

Future Prospects

Demand for durable, UV-resistant plastics shows no sign of slowing down. Sustainable building products, electric vehicles, and smart packaging all require longer life and higher safety. Industry insiders keep pushing for even lower leach rates and better compatibility with recycling. Regulatory focus on microplastics and chemical additives challenges chemists to keep improving purification, reducing off-gassing, and mapping any secondary breakdown routes. Some startups and big players already scan for bio-based or self-healing additives, but for now, this benzotriazole offers unbeatable performance per gram. I see real opportunities in emerging applications—wearables, solar films, and next-gen displays ask for protection without any color change or loss of transparency. Open research, transparent supply chains, and third-party tests will stay central as customers demand greener, safer, and longer-lasting consumer goods.



What is the primary use of 2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole?

Keeping Plastics and Coatings from Fading Fast

Whether you’re spending a summer grilling in the backyard or stepping into a car that’s parked outside all day, you’ve noticed that sun does a number on anything left out in the open. Colors start to fade, plastics crack, and painted surfaces lose their shine. A lesser-known chemical, 2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole, tackles this exact problem. Manufacturers call it a UV absorber. Its main job is to protect plastics, coatings, and sometimes adhesives from sunlight damage.

Why We All Care About Sun Damage

Most people ignore what’s going on at the molecular level. Sunlight, especially in the UV range, breaks down chemical bonds in plastics and finishes. Over time, this causes surfaces to discolor or weaken—think of garden chairs that go from green to bleached gray or the dashboard that starts as black and ends up brittle. The costs add up. Homeowners replace faded outdoor furniture. Car owners pay for reupholstery or new dashboards. City planners budget for updating park benches far sooner than planned.

UV absorbers work by capturing high-energy UV rays before they can split up molecules in plastics and paints. This specific compound stands out because it handles both the short UVB and the longer UVA rays, so the protection runs wide. I’ve seen this in action with clear coatings for cars. You can park two identical vehicles side by side—one with a UV absorber in the clear coat, the other without—and just a few seasons later, the difference jumps out. The protected car stays shinier with no hazing on the surface. That kind of shield keeps materials from aging fast, which explains why global plastic manufacturers spend big to secure these additives.

Safety Counts Too

While safety matters for any chemical, this compound gets extra scrutiny since it often ends up in toys, food packaging, and coatings people touch every day. Research points to low toxicity if handled properly and used within recommended limits. The alternative—materials breaking down into less-predictable fragments—brings health questions of its own. So industries keep studying the environmental footprint, especially as microplastics and additive leaching draw more headlines. Anyone worried about this can look for goods marked as compliant with local safety standards, like the EU REACH regulation or the FDA’s guides.

Better Products and Smarter Solutions

For a long time, options for UV stability ran pretty thin. Some pigments helped, but they changed the way colors looked. Adding glass fibers bumped up strength but couldn’t tackle fading. With UV absorbers like this, designers now have more control—clear plastics stand up to sunlight, colored items keep looking sharp, and surfaces don’t lose their finish before their time.

Still, nothing lasts forever. Long-term solutions could come from smarter polymer designs or coatings that self-heal under stress. For now, compounds like 2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole remain a frontline tool for manufacturers who want products to not just start out fresh, but to stay that way.

Is 2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole safe for use in plastics and polymers?

Understanding This Chemical's Role

Most plastics and coatings struggle against the constant attack from sunlight. Ultraviolet radiation tears apart molecules, causing fading, brittleness, and cracks. That’s where stabilizers such as 2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole come in. Chemists call it a UV absorber. In practical terms, it helps plastics last longer outdoors, keeping lawn furniture from falling apart or automotive dashboards from turning chalky. This specific compound offers a powerful shield, grabbing harmful UV rays before the rays have a chance to slice up the plastic chains.

Peeking Into Safety Records

Anyone who grew up hearing about “plastics leaching chemicals” into food or water knows the concerns people carry. Some additives earn a bad reputation for good reason. Consumers still recall the worries about BPA in baby bottles, which pushed many to demand safer alternatives. So, every time a new chemical gets added to products, especially where kids might chew or touch them, a tough question follows: is it safe?

Research on 2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole looks for toxicity, accumulation inside the body, and even how it interacts with the environment. Studies reviewed by major regulatory agencies, such as the European Chemicals Agency (ECHA), show low acute toxicity in mammals and little evidence for cancer with typical exposures. Lab animals fed or exposed to high doses did not show alarming effects when exposure stayed below strict limits. Unlike some other benzotriazoles, this one isn’t flagged as a reproductive toxin or endocrine disruptor.

These assessments still leave some room for improvement. Research from environmental science teams raises valid questions about where such compounds end up after leaving products and whether fish or aquatic bugs run into trouble. Benzotriazole derivatives stick around in water, and some evidence suggests persistence in streams and rivers. Though concentrations typically measure in parts per billion, small creatures living in sediment could see higher exposures over time.

Human Exposure and Risk

Most exposure happens not by touching a plastic toy but by eating, drinking, or, less commonly, breathing in dust after plastics break down. Migration studies, including those conducted by food safety agencies, repeatedly find this particular additive stays locked up well within the plastic matrix. It moves less than some notorious plasticizers. In real-world settings, it rarely appears in food at levels near safety limits set by authorities like the US FDA or EFSA.

Factory workers see higher exposure, though. They handle raw stabilizer powder as it goes into large mixers or extruders. Reliable safety protocols—a must in any modern plant—make a difference. Respirators, gloves, and proper ventilation lower the risks. Yet, every workplace must develop a culture that reinforces these habits, not just boxes ticked on a checklist.

Responsibility Beyond Labels

Even if current science points to a low risk for most users, there is value in pushing for alternatives that not only protect plastic but also break down safely after use. I’ve seen communities rally around local rivers plagued by hard-to-remove pollution. Each step taken in manufacturing—from chemists in the lab to workers at the bench—echoes down that river. Choosing the right stabilizer isn’t just a technical call; it carries public trust, leaving a mark on both product quality and environmental health.

Pursuing Safer Innovations

Many engineers and product designers track new data from toxicology and environmental studies, nudging suppliers to be open about their chemicals. Public calls for green chemistry matter, especially when they come from people whose families work or play near factories. Transparency about what goes in plastics, plus investment in testing, will keep safety from slipping through the cracks.

What are the recommended storage conditions for this product?

Why Storage Conditions Matter

Proper storage does more than safeguard a company’s investment—it protects people's health. From food and medicine to chemicals and electronics, products change when exposed to their environment. Extreme temperatures, sunlight, and humidity start a slow process that can cost both money and safety. A spoiled batch of medication does not deliver intended results. Food loses nutritional value or becomes unsafe. That kind of risk should never be overlooked.

Control Over Temperature

Daily temperature swings often go unnoticed, but products don’t forget. Imagine storing chocolate in a warm room. It melts, reshapes, and then hardens with a dull surface. Medications follow a similar trend—some lose their effectiveness if the temperature jumps above recommended levels. Manufacturers usually stamp temperature ranges on their labels because stability depends on it. Cool, dry places often turn out to be best for many goods, especially for those with active ingredients that break down over time.

Light Exposure and Its Effects

Direct sunlight has never been a friend to storage. Active compounds in medicines, for example, degrade when exposed to UV rays. Vitamins and oils turn rancid or lose their benefits. Grocery stores often keep fresh produce under special filters for this reason. Light-proof packaging helps, but the storage area itself plays a bigger role. A dark cabinet or storeroom shields products from unnecessary chemical changes.

The Problem With Moisture

No one wants clumping or mold growing in their goods. Moisture attracts fungus, bacteria, and insects. Dry storage cuts down those risks dramatically. Sachets of silica gel in packaging say plenty about the concern for humidity. People who store flour, grains, or powders see firsthand how excess dampness leads to spoilage and waste. Keeping products dry also prevents corrosion in electronics and rust in metal parts. Relative humidity in the storage space should stay below 60% unless the manufacturer suggests something different.

Choosing the Right Containers

Sometimes, even the best environment isn’t enough. Robust containers act as a second line of defense. Air-tight jars and resealable bags slow down the rate of deterioration. Metal cans prevent rodents from ruining seeds and grains. For hazardous substances, certified containers prevent leaks and accidental exposure. People working in warehouses rely on clear labeling to know what’s safe for each product—it’s about as practical as it gets.

Smart Practices at Home and in Industry

Over the years, it’s become clear through both science and personal experience that sloppy storage shortens shelf life. Buying in bulk saves money only if you store those goods well. Home pantries and industrial warehouses benefit from organization—regular checks, inventory rotation, and avoiding overcrowding. Many food safety recalls point back to storage failures that could have been prevented with a little planning.

Moving Forward: Technology and Training

Technology has stepped in to help. Modern storage often involves sensors that track temperature and humidity. Alerts go out before problems start. Routine staff training makes a noticeable difference. As people understand what’s at stake, they become part of a system that prevents waste, protects health, and preserves value. Safe storage conditions turn into more than a checklist item; they become part of a wider culture of responsibility.

How does 2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole function as a UV stabilizer?

What’s at Stake with Sunlight and Materials

People often assume that only skin faces damage from the sun, but plastics and coatings take a big hit too. Sunlight, especially the UV end, breaks down many things we use every day: outdoor furniture, car dashboards, clear films over electronics, even the packaging that keeps food fresh. When UV rays hit polymers, chains snap, color fades, and surfaces chalk or crack. Fixing that—keeping materials tough amidst relentless sunshine—matters both for cost and for the waste that comes with constant replacement.

Breaking Down the Science Behind the Stabilizer

2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole is a type of hydroxyphenyl benzotriazole. That's a mouthful, but it comes down to clever chemistry. This molecule soaks up UV light before that energy breaks apart the things we want to protect. Think of it as an umbrella embedded directly into the plastic. Instead of letting the UV rays pound away at the polymer, the stabilizer takes the hit.

Unlike some other molecules that only slow things down, this compound grabs the UV rays and turns them into tiny amounts of harmless heat. The hydroxyl group on the phenyl ring pulls double duty: snagging UV photons, then releasing energy safely through a quick chemical change. The bulky tert-butyl groups on the phenyl ring help by making the stabilizer stay put inside the polymer instead of migrating out or breaking down quickly. The chlorobenzotriazole unit adds extra resistance against degradation over time. Together, that means parts infused with this chemical fend off sunlight longer than untreated ones.

Why It’s Popular for Real-World Products

I’ve seen plastic films turn brittle in just a few months outdoors without UV protection. By mixing this stabilizer into polycarbonate or polypropylene, those same films last long enough for real use, whether on greenhouse roofs, car headlights, or packaging windows. Manufacturers want clarity—no yellowing, no haze. This stabilizer keeps materials clear, where some other additives can fog things up.

People sometimes overlook how much maintenance comes from fading and cracking. Deck chairs, construction panels, even garden hoses all last years longer thanks to this compound. It means fewer cracked parts in playgrounds. It means buildings hold their sleek, new look. In medical device packaging, a bit of this additive ensures that clear films keep a barrier against germs and moisture until the product gets used.

Addressing Safety and Sustainability

Some critics worry about added chemicals in plastics. Strict regulations limit how much stabilizer can go into items that touch food or skin. Independent labs have checked for migration and breakdown products, giving makers data points to keep risk low. Europe, the US, and major Asian markets maintain tight oversight. As someone who follows green chemistry, I think about long-term impacts too. Over time, more producers have tuned this molecule to resist leaching, and some even recover or recycle used plastics to steer clear of build-up in the environment.

One promising direction involves more efficient use—tailoring stabilizer levels to each product, so there’s enough protection without waste. Some labs now combine this stabilizer with antioxidants or hindered amine light stabilizers for teamwork against both sunlight and heat. This lets everyone stretch resources while guarding against the elements.

Looking Forward

Keeping outdoor products bright and sturdy isn’t just about cosmetics. Less material wasted, more safety, fewer disruptions. The science behind this stabilizer shows how chemistry shapes the world in quiet, powerful ways—so the things we rely on stay reliable, season after season.

Are there any known hazards or handling precautions for this chemical?

Everyday Chemicals, Everyday Risks

Most people picture something out of a chemistry lab when they hear “hazardous chemical,” but the truth is, some of the most common risks crop up with things found in garages, under kitchen sinks, or at the edge of a gardener’s shed. Years ago, a bottle of bleach slipped off my laundry shelf and splashed on my jeans. Instant panic. That sharp smell, stinging eyes, and the sight of colors fading from denim said enough. It doesn’t take a degree in chemistry to respect what’s inside those bottles.

The Basic Dangers

Some chemicals burn skin, others gnaw away at lungs or eyes, while a few, at the right dose, poison slowly and silently over time. I learned the hard way that even a simple vinegar-ammonia mix creates nasty fumes. Certain solvents delight in leaping to flame if a nearby tool throws a spark. By reading reports from the Centers for Disease Control, I saw how chemical mishaps fill emergency rooms each year, especially among folks who never expected a little bottle could knock them down so fast.

Gloves, Goggles, and Good Sense

During work at a hardware store, I got to know the value of thick gloves and basic eye protection firsthand. One slip of drain cleaner stings fast. Personal protective equipment separates us from disaster. The American Industrial Hygiene Association points out that something simple like a splash-proof face shield can prevent months of pain and medical bills. Open windows and fans pull nasty vapors outside, away from lungs. Printed warnings sometimes get ignored until something goes wrong, so reading the label each time keeps surprises away.

Storage and Cleanup

Once, I saw a neighbor store gasoline in an old milk jug. Dangerous doesn’t cover it. Good containers make all the difference. Any chemical labeled “flammable” should stay far from water heaters and open flames. Well-ventilated sheds or garage corners work best. Rags soaked with certain chemicals—varnishes, paint thinners—caught fire on a summer day, so oily waste belongs in closed metal cans. Cleaning up right away, even for small spills, stops trouble before it starts.

Training and Education Fix Blind Spots

Mistakes often come from not knowing what’s in a bottle. At a maintenance job, I saw coworkers fall into a routine of mixing products just to get the job done faster. Employers who offer training, or at least a rundown of basic risks, cut accidents down. The Occupational Safety and Health Administration publishes easy-to-read bulletins on dozens of chemicals. Taking five minutes to scan one of those sheets beats two weeks in a hospital bed.

Proper Disposal Stops a Chain Reaction

Flushing chemicals or tossing them into a regular trash can sets off a chain nobody wants. I remember attending a community collection day, where workers sorted paint, solvents, and bug killers. Organized collection stops leaks from seeping into soil or sneaking into water lines. It keeps towns safer and saves on expensive cleanups. City and county waste programs hand out solid advice and update drop-off days online for anyone willing to look.

Looking Ahead

It only takes a few right steps—reading labels, keeping gear handy, learning from others’ mistakes—to bend the odds our way. Knowledge and respect for what’s in a bottle or barrel matter more than fancy equipment or endless caution tape. Safety depends largely on habits, not just instructions on a label.

2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole