MSDS: (1R,2R)-(-)-1,2-Diaminocyclohexane L-tartrate

Identification

Chemical Name: (1R,2R)-(-)-1,2-Diaminocyclohexane L-tartrate
Synonyms: L-tartaric acid salt of (1R,2R)-diaminocyclohexane
CAS Number: 68516-73-4
Recommended Use: Chiral agent, catalyst precursor, intermediate for synthesis
Supplier Details: Manufacturer contact information, mailing address, emergency contact number
Product Code: Product-specific identifier or batch code, if available

Hazard Identification

GHS Classification: Not classified as hazardous under GHS
Signal Word: None assigned under current classification
Hazard Statements: Not expected to be a health or environmental hazard under normal conditions
Pictograms: No pictograms required
Precautionary Statements: Avoid inhalation of dust, minimize skin and eye contact, handle in well-ventilated areas
Other Hazards: May cause mild irritation to eyes, skin, or respiratory tract, especially as dust; not known to cause acute toxicity or chronic effects
Potential Environmental Impact: Low potential for bioaccumulation or persistence, but control release to environment

Composition / Information on Ingredients

Chemical Identity: (1R,2R)-(-)-1,2-Diaminocyclohexane L-tartrate
Concentration: Typically >98%
Impurities: Trace levels of unreacted starting materials or byproducts (<2%)
Molecular Formula: C10H20N2·C4H6O6
Molecular Weight: 308.36 g/mol
Other Components: No other additives or binders present in significant quantity

First Aid Measures

Inhalation: Move to fresh air, support breathing as needed, seek medical advice if symptoms develop
Skin Contact: Wash skin thoroughly with soap and water, remove contaminated clothing, pay attention to irritated areas
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy, continue rinsing, consult a healthcare provider if irritation persists
Ingestion: Rinse mouth with water, avoid inducing vomiting, seek medical attention if unwell
Most Important Symptoms: Mild irritation to respiratory tract, discomfort in eyes or skin, no serious acute toxicity documented
Advice for Physicians: Treat based on symptoms, provide supportive care

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical, foam or carbon dioxide
Unsuitable Extinguishing Media: Do not use high-pressure water jet, as contamination of the wider environment could occur
Specific Hazards Arising from Chemical: Combustion may release carbon oxides, nitrogen oxides, possibly traces of hydrogen cyanide
Protective Equipment for Firefighters: Self-contained breathing apparatus, full protective gear
Advice for Firefighters: Move containers from fire area if safe, spray cool water to prevent overheating, avoid inhaling fumes or decomposition products
Explosion Data: Not sensitive to mechanical impact or static discharge

Accidental Release Measures

Personal Precautions: Ventilate the area, avoid creating dust clouds, wear appropriate protective equipment (gloves, goggles, respiratory protection if required)
Environmental Precautions: Prevent release to drains, soil, or water sources
Containing/Collecting Spills: Sweep up spilled substance with minimum dust generation, transfer to suitable waste container, clean surfaces with damp cloth to remove residues
Reference to Other Sections: See guidance under handling, storage, and disposal for further information

Handling and Storage

Precautions for Handling: Work in well-ventilated environments, minimize dust buildup, avoid inhaling material, use gloves and eye protection, wash hands after handling
Conditions for Safe Storage: Store in tightly closed original container, keep in a cool, dry, well-ventilated location, segregate from strong acids, oxidizers, and incompatible materials
Special Considerations: Label containers clearly, avoid direct sunlight or extreme heat, keep out of reach of children or untrained personnel, inspect containers for damage or leaks regularly

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established limits for this substance, maintain airborne dust levels as low as possible
Engineering Controls: Local exhaust or process enclosure recommended for high-dust activities, ensure eyewash stations and emergency showers accessible
Personal Protective Equipment: Chemical-resistant gloves, tightly fitting goggles, protective clothing such as lab coat or apron
Respiratory Protection: NIOSH-approved particulate filter mask if dust levels increase above comfort threshold
Other Protective Measures: Prohibit eating, drinking or smoking in work area, remove contaminated clothing promptly

Physical and Chemical Properties

Appearance: White to off-white crystalline powder
Odor: Slight, non-offensive
Odor Threshold: Not established
pH (solution): ~5–6 (in water)
Melting Point/Range: Approx. 180°C (decomposes)
Boiling Point: Not applicable (decomposes on heating)
Flash Point: Not flammable
Evaporation Rate: Not relevant (solid at ambient temperature)
Flammability: Not classified as flammable
Vapor Pressure: Negligible at room temperature
Vapor Density: Not applicable
Solubility: Soluble in water, slightly soluble in organic solvents
Partition Coefficient (log Kow): Data not available
Specific Gravity: Approx. 1.5 g/cm³
Decomposition Temperature: Decomposes above 180°C
Viscosity: Not applicable

Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures
Reactivity: Low, not expected to undergo violent reactions
Conditions to Avoid: Excessive heat, direct sunlight, high humidity, contact with incompatible substances
Incompatible Materials: Strong acids, oxidizing agents, strong bases
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, nitrogen oxides, possibly traces of ammonia or hydrogen cyanide on combustion
Possibility of Hazardous Reactions: Hazardous polymerization will not occur

Toxicological Information

Routes of Exposure: Inhalation, skin contact, eye contact, ingestion
Acute Toxicity: No data showing acute toxicity in humans or animals at typical concentrations
Skin Corrosion/Irritation: May cause mild irritation with prolonged or repeated contact
Serious Eye Damage/Irritation: Temporary discomfort or redness upon exposure
Respiratory Sensitization: No known sensitizing effect, use appropriate protection during dusty work
Germ Cell Mutagenicity: No data suggesting genetic toxicity
Carcinogenicity: Not classified as carcinogenic by IARC, NTP, OSHA
Reproductive Toxicity: No evidence of reproductive harm
Other Information: Personal experience handling similar diamine tartrate salts has revealed no unexpected reactions or injuries, provided recommended safety protocols are observed

Ecological Information

Ecotoxicity: Not expected to pose significant hazard to aquatic or terrestrial systems in small quantities
Persistence and Degradability: Likely to undergo biodegradation in natural environments
Bioaccumulation Potential: Low potential based on structure and solubility
Mobility in Soil: Water solubility suggests potential for minor mobility, but no evidence of long-range transport or persistence
Other Adverse Effects: Avoid release in large volumes or repeated spills to reduce localized impact on soil organisms or water systems

Disposal Considerations

Waste Treatment Methods: Dispose in accordance with federal, state, and local regulations
Product Disposal: Treat chemically contaminated waste as general laboratory solid waste or offer for incineration at approved facility
Packaging Disposal: Empty containers should be disposed or recycled in conformity with regulations, avoid reusing packaging for other substances
Special Considerations: Prevent significant discharge to waterways or sewer systems, consult with waste management professionals if uncertain

Transport Information

UN Number: Not regulated for transport
UN Proper Shipping Name: Not applicable
Transport Hazard Class: Non-hazardous for all regulated methods
Packing Group: Not assigned
Environmental Hazards: No specific risk identified, avoid large accidental releases
Transport Precautions: Pack securely to minimize dust, keep separate from food and feedstuffs

Regulatory Information

TSCA Status: Listed or exempt
EINECS/ELINCS: Listed, according to EU Inventory
SARA Title III (Sections 302, 311/312, 313): Not subject to reporting
California Proposition 65: Not listed
REACH Status: Not classified as a substance of high concern
Other Applicable Regulations: All usual chemical handling and safety regulations apply, ensure compliance with regional legislation